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Tris[4-bromo-2-(methyl-imino-meth-yl)phenolato-?(2) N,O]cobalt(III).

ABSTRACT: In the title compound, [Co(C8H7BrNO)3], the Co(III) ion is coordinated in a slightly distorted octa-hedral environment by three N atoms and three O atoms from three bidentate 4-bromo-2-(methyl-imino-meth-yl)phenolate ligands. The dihedral angles between the benzene rings are 82.6?(2), 57.1?(2) and 62.9?(2)°. In the crystal, mol-ecules are linked by pairs of weak C-H?Br hydrogen bonds, forming inversion dimers.

SUBMITTER: Huang QP

PROVIDER: S-EPMC3884257 | biostudies-literature | 2013 Oct

REPOSITORIES: biostudies-literature

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Tris[4-bromo-2-(methyl-imino-meth-yl)phenolato-κ(2) N,O]cobalt(III).

Huang Qiu-Ping QP Zhang Chun-Lian CL Zhao Ru-Xia RX Yang Li L Jiang Xi-Fu XF

Acta crystallographica. Section E, Structure reports online 20131016 Pt 11

In the title compound, [Co(C8H7BrNO)3], the Co(III) ion is coordinated in a slightly distorted octa-hedral environment by three N atoms and three O atoms from three bidentate 4-bromo-2-(methyl-imino-meth-yl)phenolate ligands. The dihedral angles between the benzene rings are 82.6 (2), 57.1 (2) and 62.9 (2)°. In the crystal, mol-ecules are linked by pairs of weak C-H⋯Br hydrogen bonds, forming inversion dimers. ...[more]

PMID: 24454033

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