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Tris[2,4-dichloro-6-(ethyl-imino-meth-yl)phenolato-?(2)N,O]cobalt(III).

ABSTRACT: The asymmetric unit of the title compound, [Co(C(9)H(8)Cl(2)NO)(3)], contains three independent mol-ecules. In each mol-ecule, the Co(III) ion is coordinated by an O atom and an N atom from three bidentate 2,4-dichloro-6-(ethyl-imino-meth-yl)phenolate ligands in a slightly distorted octa-hedral environment. In the crystal, a weak C-H?Cl hydrogen bond is observed.

SUBMITTER: Huang QP

PROVIDER: S-EPMC3414116 | biostudies-literature | 2012 Aug

REPOSITORIES: biostudies-literature

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Tris[2,4-dichloro-6-(ethyl-imino-meth-yl)phenolato-κ(2)N,O]cobalt(III).

Huang Qiu Ping QP Guo Jing Jing JJ Zhang Yi Dong YD Zhang Shu Hua SH

Acta crystallographica. Section E, Structure reports online 20120710 Pt 8

The asymmetric unit of the title compound, [Co(C(9)H(8)Cl(2)NO)(3)], contains three independent mol-ecules. In each mol-ecule, the Co(III) ion is coordinated by an O atom and an N atom from three bidentate 2,4-dichloro-6-(ethyl-imino-meth-yl)phenolate ligands in a slightly distorted octa-hedral environment. In the crystal, a weak C-H⋯Cl hydrogen bond is observed. ...[more]

PMID: 22904723

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