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Bis[4-(2-aza-niumyleth-yl)piperazin-1-ium] di-?-sulfido-bis-[disulfido-germanate(II)].

ABSTRACT: In the title compound, (C(6)H(17)N(3))(2)[Ge(2)S(6)], the dimeric [Ge(2)S(6)](4-) anion is formed by two edge-sharing GeS(4) tetra-hedral units. The average terminal and bridging Ge-S bond lengths are 2.164?(2) and 2.272?(8)?Å, respectively. The dimeric inorganic anions and the organic piperazinium cations are organized into a three-dimensional network by N-H?S hydrogen bonds.

SUBMITTER: Zhang BB

PROVIDER: S-EPMC3379143 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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Bis[4-(2-aza-niumyleth-yl)piperazin-1-ium] di-μ-sulfido-bis-[disulfido-germanate(II)].

Zhang Bei-Bei BB Xu Chao C Duan Taike T Chen Qun Q Zhang Qian-Feng QF

Acta crystallographica. Section E, Structure reports online 20120526 Pt 6

In the title compound, (C(6)H(17)N(3))(2)[Ge(2)S(6)], the dimeric [Ge(2)S(6)](4-) anion is formed by two edge-sharing GeS(4) tetra-hedral units. The average terminal and bridging Ge-S bond lengths are 2.164 (2) and 2.272 (8) Å, respectively. The dimeric inorganic anions and the organic piperazinium cations are organized into a three-dimensional network by N-H⋯S hydrogen bonds. ...[more]

PMID: 22719364

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