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Bis[3,3'-(piperazine-1,4-di-yl)-dipropan-aminium] di-?(2)-sulfido-bis-[disulfido-german-ate(IV)].

ABSTRACT: In the title compound, (C(10)H(26)N(4))(2)[Ge(2)S(6)], the dimeric [Ge(2)S(6)](4-) anion formed by two edge-sharing GeS(4) tetra-hedral units lies around an inversion centre. The average terminal and bridging Ge-S bond lengths are 2.162?(7) and 2.267?(15)?Å, respectively. The inorganic anions and organic cations are organized into a three-dimensional network by numerous N-H?S hydrogen bonds.

SUBMITTER: Wang NN

PROVIDER: S-EPMC3414115 | biostudies-literature | 2012 Aug

REPOSITORIES: biostudies-literature

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Bis[3,3'-(piperazine-1,4-di-yl)-dipropan-aminium] di-μ(2)-sulfido-bis-[disulfido-german-ate(IV)].

Wang Nian-Nian NN Xu Chao C Duan Taike T Chen Qun Q Zhang Qian-Feng QF

Acta crystallographica. Section E, Structure reports online 20120710 Pt 8

In the title compound, (C(10)H(26)N(4))(2)[Ge(2)S(6)], the dimeric [Ge(2)S(6)](4-) anion formed by two edge-sharing GeS(4) tetra-hedral units lies around an inversion centre. The average terminal and bridging Ge-S bond lengths are 2.162 (7) and 2.267 (15) Å, respectively. The inorganic anions and organic cations are organized into a three-dimensional network by numerous N-H⋯S hydrogen bonds. ...[more]

PMID: 22904722

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