Browse
Submit Data
Databases
API
Help

Dataset Information

13 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

(E)-(2,4-Dichloro-benzyl-idene)amino cyclo-propane-carboxyl-ate.

ABSTRACT: In the title compound C(11)H(9)Cl(2)NO(2), the dihedral angle between the benzene and cyclo-propane ring planes is 89.95?(13)°. The carbon-yl-oxime grouping is almost coplanar with the benzene ring [dihedral angle = 4.08?(6)°]. In the crystal, mol-ecules are linked by C-H?O inter-actions into [100] chains.

SUBMITTER: Wang MY

PROVIDER: S-EPMC3379204 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

(E)-(2,4-Dichloro-benzyl-idene)amino cyclo-propane-carboxyl-ate.

Wang Mei-Yi MY Zhang Ya Y

Acta crystallographica. Section E, Structure reports online 20120502 Pt 6

In the title compound C(11)H(9)Cl(2)NO(2), the dihedral angle between the benzene and cyclo-propane ring planes is 89.95 (13)°. The carbon-yl-oxime grouping is almost coplanar with the benzene ring [dihedral angle = 4.08 (6)°]. In the crystal, mol-ecules are linked by C-H⋯O inter-actions into [100] chains. ...[more]

PMID: 22719402

Similar Datasets

(E)-(4-Bromo-benzyl-idene)amino cyclo-propane-carboxyl-ate.

Project description:In the title compound, C(11)H(10)BrNO(2), the dihedral angle between the benzene and cyclo-propane ring planes is 49.4?(3)°. The C-C-N-O torsion angle is -175.1?(3)°, which indicates that the C=N double bond is in the E configuration.

| S-EPMC3275239 | biostudies-literature

2,6-Bis(2,4-dichloro-benzyl-idene)cyclo-hexa-none.

Project description:The title compound, C(20)H(14)Cl(4)O, was prepared from a mixture of 2,4-dichloro-benzophenone and cyclo-hexa-none. The dihedral angles formed by the cyclohexane ring and two benzene rings are 39.18?(2) and 60.72?(2)°. There are some weak intra-molecular C-H?O and C-H?Cl hydrogen-bond contacts in the crystal structure.

| S-EPMC2962235 | biostudies-literature

2-Amino-pyridinium 1-phenyl-cyclo-propane-1-carboxyl-ate.

Project description:In the title salt, C(5)H(7)N(2) (+)·C(10)H(9)O(2) (-), 2-amino-pyridine and 1-phenyl-cyclo-propane-1-carb-oxy-lic acid crystallize together, forming a 2-amino-pyridinium-carboxyl-ate supra-molecular heterosynthon involving two N-H?O hydrogen bonds, which in turn dimerizes to form a four-component supra-molecular unit also sustained by N-H?O hydrogen bonding. A C-H?? inter-action between a pyridine C-H group and the centroid of the phenyl ring of the anion further stabilizes the four-component supra-molecular unit. The overall crystal packing also features C-H?O inter-actions.

| S-EPMC3011640 | biostudies-literature

2-[(E)-(2,4-Dichloro-benzyl-idene)amino]-isoindoline-1,3-dione.

Project description:In the title compound, C(15)H(8)Cl(2)N(2)O(2), the mol-ecule adopts an E configuration about the central C=N double bond. The isoindoline ring is essentially planar, with a maximum deviation of 0.019?(2)?Å. The dihedral angle between the isoindoline ring and the dichloro-substituted benzene ring is 6.54?(9)°. An intra-molecular C-H?O hydrogen bond occurs. A short Cl?Cl contact of 3.4027?(9)?Å is present in the crystal structure. The crystal packing is further stabilized by weak C-H?? inter-actions.

| S-EPMC3151809 | biostudies-literature

Ethyl 3-(2,4-dichloro-benzyl-idene)carbazate.

Project description:The title compound, C(10)H(10)Cl(2)N(2)O(2), was prepared by the reaction of ethyl carbazate and 2,4-dichloro-benzaldehyde. In the crystal structure, mol-ecules are linked by inter-molecular N-H?O hydrogen bonds, forming extended chains along [001].

| S-EPMC2971455 | biostudies-literature

(2,4-Dihydroxy-benzyl-idene)dimethyl-ammonium dichloro-phosphinate.

Project description:In the title compound, C(9)H(12)NO(2) (+)·Cl(2)PO(2) (-), the mol-ecular skeleton of the cation is nearly planar with an r.m.s. deviation of 0.0336?Å. In the crystal structure, inter-molecular O-H?O hydrogen bonds link cations and anions into chains running along [10].

| S-EPMC2968160 | biostudies-literature

N'-(2,4-Dichloro-benzyl-idene)-2-methyl-benzohydrazide.

Project description:In the title hydrazone compound, C(15)H(12)Cl(2)N(2)O, the dihedral angle between the two benzene rings is 12.2?(2)°. In the crystal, mol-ecules are linked through inter-molecular N-H?O hydrogen bonds, forming forming C(4) chains propagating in [001].

| S-EPMC3011553 | biostudies-literature

N'-(2,4-Dichloro-benzyl-idene)-2-fluoro-benzohydrazide.

Project description:The mol-ecule of the title compound, C(14)H(9)Cl(2)FN(2)O, exists in a trans configuration with respect to the methyl-idene unit and the benzene rings form a dihedral angle of 8.1?(2)°. In the crystal, mol-ecules are linked through N-H?O hydrogen bonds into C(4) chains propagating in [100].

| S-EPMC3051578 | biostudies-literature

2-Chloro-N'-(2,4-dichloro-benzyl-idene)benzohydrazide.

Project description:The title Schiff base compound, C(14)H(9)Cl(3)N(2)O, exists in a trans configuration with respect to the C=N bond and the dihedral angle between the two benzene rings is 13.5?(2)°. In the crystal, inter-molecular N-H?O hydrogen bonds link adjacent mol-ecules into extended C(4) chains propagating along the c-axis direction.

| S-EPMC2983764 | biostudies-literature

N'-(2,4-Dichloro-benzyl-idene)-3-methoxy-benzohydrazide.

Project description:There are two independent mol-ecules in the asymmetric unit of the title compound, C(15)H(12)Cl(2)N(2)O(2). The dihedral angle between the two benzene rings is 27.6?(4)° in one mol-ecule and 16.4?(4)° in the other. Both mol-ecules adopt an E configuration about the C=N bonds. In the crystal structure, mol-ecules are linked through inter-molecular N-H?O hydrogen bonds, forming chains in the a-axis direction.

| S-EPMC2983793 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data