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3-{[Bis(pyridin-2-ylmeth-yl)amino]-meth-yl}-2-hy-droxy-5-methyl-benz-aldehyde.

ABSTRACT: In the title compound, C(21)H(21)N(3)O(2), the pyridine rings and the benzene ring lie in a propeller arrangement around the central tertiary amine N atom. The dihedral angles formed by the benzene ring with the pyridine rings are 61.0?(3) and 49.6?(3)°, while the dihedral angle between the pyridine rings is 69.7?(3)°. The mol-ecular conformation is stabilized by intramolecular bifurcated O-H?N hydrogen bonds. In the crystal, inversion dimers are formed via pairs of C-H?N hydrogen bonds.

SUBMITTER: Wang RX

PROVIDER: S-EPMC3379269 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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3-{[Bis(pyridin-2-ylmeth-yl)amino]-meth-yl}-2-hy-droxy-5-methyl-benz-aldehyde.

Wang Ruo-Xu RX Gao Da-Zhi DZ Ye Fan F Wu Yan-Fei YF Zhu Dun-Ru DR

Acta crystallographica. Section E, Structure reports online 20120512 Pt 6

In the title compound, C(21)H(21)N(3)O(2), the pyridine rings and the benzene ring lie in a propeller arrangement around the central tertiary amine N atom. The dihedral angles formed by the benzene ring with the pyridine rings are 61.0 (3) and 49.6 (3)°, while the dihedral angle between the pyridine rings is 69.7 (3)°. The mol-ecular conformation is stabilized by intramolecular bifurcated O-H⋯N hydrogen bonds. In the crystal, inversion dimers are formed via pairs of C-H⋯N hydrogen bonds. ...[more]

PMID: 22719467

Similar Datasets

Crystal structure of 3-[({2-[bis-(2-hy-droxy-benz-yl)amino]-eth-yl}(2-hy-droxy-benz-yl)amino)-meth-yl]-2-hydroxy-5-methyl-benzaldehyde.

Project description:The non-symmetric title mol-ecule, C32H34N2O5, is based on a tetra-substituted ethyl-enedi-amine backbone. The mol-ecular structure consists of three hy-droxy-benzyl groups and one 2-hy-droxy-5-methyl-benzaldehyde group bonded to the N atoms of the di-amine unit. The ethyl-enedi-amine skeleton shows a regular extended conformation, while the spatial orientation of the phenol arms is governed by hydrogen bonds. In the 2-hy-droxy-5-methyl-benzaldehyde group, an intra-molecular S(6) O-H?O hydrogen bond is observed between the alcohol and aldehyde functions, and the neighbouring phenol arm participates in an intra-molecular S(6) O-H?N hydrogen bond. The third phenol group is involved in a bifurcated intra-molecular hydrogen bond with graph-set notation S(6) for O-H?N and O-H?O intra-molecular hydrogen bonds between neighbouring amine and phenol arms, respectively. Finally, the fourth phenol group acts as an acceptor in a bifurcated intra-molecular hydrogen bond and also acts as donor in an inter-molecular hydrogen bond, which connects inversion-related mol-ecules into dimers with R 4 (4)(8) ring motifs.

| S-EPMC4257411 | biostudies-literature

[2-({Benz-yl[2-(benz-yl{5-methyl-2-oxido-3-[(pyridin-2-ylmeth-yl)imino-meth-yl]benz-yl}amino)-eth-yl]aza-nium-yl}meth-yl)-4-methyl-6-[(pyridin-2-ylmeth-yl)imino-meth-yl]phenolato]nickel(II) perchlorate methanol disolvate.

Project description:In the solvated title complex, [Ni(C(46)H(47)N(6)O(2))]ClO(4)·2CH(4)O, the coordination sphere around the Ni(II) ion can be described as distorted cis-NiO(2)N(4) octa-hedral defined by two phenolate O atoms and four N atoms from the hexa-dentate ligand. An intra-molecular bifurcated N-H?(N,O) hydrogen bond helps to establish the conformation of the complex mol-ecule. In the crystal, the components are connected by O-H?O and C-H?O hydrogen bonds.

| S-EPMC3379195 | biostudies-literature

2-{[{2-Hy-droxy-3-[2-methyl-5-(propan-2-yl)phen-oxy]prop-yl}(pyridin-2-ylmeth-yl)amino]-meth-yl}phenol.

Project description:In the title racemic compound, C(26)H(32)N(2)O(3), an intra-molecular O-H?N hydrogen bond is formed between the phenolic OH group and the tertiary amine N atom. Another O-H?N hydrogen bond that is formed between the OH group and the pyridine N atom links the mol-ecules into a polymeric chain extending along the a axis. The structure is further stabilized by intramolecular and intermolecular C-H?O interactions.

| S-EPMC3152006 | biostudies-literature

[6-(Hy-droxy-meth-yl)pyridin-2-yl]methyl ferrocene-1-carboxyl-ate.

Project description:The crystal structure of the title ferrocene derivative, [Fe(C(5)H(5))(C(13)H(12)NO(3))], shows strong inter-molecular O-H?N hydrogen bonds between the alcohol function and the pyridine group of a neighbouring mol-ecule, while the pyridine function forms another hydrogen bond with the alcohol function of another neighbouring mol-ecule, resulting in the formation of chains along the a-axis direction.

| S-EPMC3247539 | biostudies-literature

2-(Hy-droxy-meth-yl)pyridin-3-ol.

Project description:In the crystal structure of the title compound, C(6)H(7)NO(2), the mol-ecules are are linked by inter-molecular O-H?N and O-H?O hydrogen bonds; ?-? stacking is observed between parallel pyridine rings of adjacent mol-ecules [centroid-to-centroid distance = 3.7649?(12)?Å].

| S-EPMC3295493 | biostudies-literature

Bis[N-(2-hy-droxy-eth-yl)-N-propyl-dithio-carbamato-?S,S']bis-(4-{[(pyridin-4-yl-methyl-idene)hydrazinyl-idene]meth-yl}pyridine-?N)cadmium.

Project description:The complete mol-ecule of the title compound, [Cd(C(6)H(12)NOS(2))(2)(C(12)H(10)N(4))(2)], is generated by crystallographic inversion symmetry. The distorted octa-hedral trans-N(2)S(4) donor set for the Cd(2+) ion is defined by two symmetrically S,S'-chelating dithio-carbamate anions and two pyridine N atoms derived from two monodentate 4-pyridine-aldazine (or 4-{[(pyridin-4-yl-methyl-idene)hydrazinyl-idene}meth-yl]pyridine) mol-ecules [dihedral angle between the aromatic rings = 17.33?(8)°]. In the crystal, mol-ecules are connected into a supra-molecular chain via O-H?N hydrogen bonds involving the 4-pyridine-aldazine N atoms not involved in coordination to cadmium. Weak C-H?O and C-H?N links consolidate the packing.

| S-EPMC3052135 | biostudies-literature

2-{[(2-Hy-droxy-3,5-dimethyl-benz-yl)(meth-yl)amino]-meth-yl}-4,6-dimethyl-phenol.

Project description:In the title compound, C(19)H(25)NO(2), the dihedral angle between the benzene rings is 53.15?(8)°. One of the -OH groups forms an intra-molecular O-H?N link, generating an S(6) ring. The other -OH group forms an inter-molecular O-H?N hydrogen bond in the crystal, generating centrosymmetric R(2) (2)(20) loops.

| S-EPMC3379400 | biostudies-literature

2,4-Di-tert-butyl-6-({[2-(di-methyl-amino)-eth-yl](2-hy-droxy-benz-yl)amino}-meth-yl)phenol.

Project description:The title compound, C26H40N2O2, has both its N atoms in trigonal-pyramidal geometries. The mol-ecular structure is stabilized by O-H?N and C-H?O hydrogen bonds. In the crystal, C-H?? inter-actions lead to the formation of a supramolecular helical chain along the b-axis direction.

| S-EPMC4051019 | biostudies-literature

Bis[?-(E)-N-(pyridin-3-yl-methyl-idene)hy-droxy-amine]-?(2) N (1):N (3);?(2) N (3):N (1)-bis-{[(E)-N-(pyridin-3-yl-methyl-idene-?N)hy-droxy-amine]-silver(I)} dinitrate.

Project description:In the centrosymmetric dinuclear title Ag(I) compound, [Ag2(C6H6N2O)4](NO3)2, the aromatic amine-coordinated Ag(I) atom is further bridged by two hydroxyl-amine mol-ecules that use aromatic and oxime N atoms for bridging, and it exists in a distorted trigonal-planar geometry. In the crystal, the nitrate anions link to the dinuclear compound mol-ecules via O-H?O hydrogen bonds, generating a chain running along the a-axis direction.

| S-EPMC3588788 | biostudies-literature

Crystal structure of an eight-coordinate terbium(III) ion chelated by N,N'-bis-(2-hy-droxy-benz-yl)-N,N'-bis-(pyridin-2-ylmeth-yl)ethyl-enedi-amine (bbpen(2-)) and nitrate.

Project description:The reaction of terbium(III) nitrate penta-hydrate in aceto-nitrile with N,N'-bis-(2-hy-droxy-benz-yl)-N,N'-bis-(pyridin-2-ylmeth-yl)ethyl-enedi-amine (H2bbpen), previously deprotonated with tri-ethyl-amine, produced the mononuclear compound [N,N'-bis-(2-oxidobenzyl-κO)-N,N'-bis-(pyridin-2-ylmethyl-κN)ethylenedi-amine-κ(2) N,N'](nitrato-κ(2) O,O')terbium(III), [Tb(C28H28N4O2)(NO3)]. The mol-ecule lies on a twofold rotation axis and the Tb(III) ion is eight-coordinate with a slightly distorted dodeca-hedral coordination geometry. In the symmetry-unique part of the mol-ecule, the pyridine and benzene rings are both essentially planar and form a dihedral angle of 61.42 (7)°. In the mol-ecular structure, the N4O4 coordination environment is defined by the hexa-dentate bbpen ligand and the bidentate nitrate anion. In the crystal, a weak C-H⋯O hydrogen bond links mol-ecules into a two-dimensional network parallel to (001).

| S-EPMC4331920 | biostudies-literature

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