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O-Propyl N-phenyl-thio-carbamate.

ABSTRACT: Two independent mol-ecules comprise the asymmetric unit in the title thio-carbamide derivative, C(10)H(13)NOS. These differ in the relative orientations of terminal ethyl groups [C-C-C-O torsion angles = -66.95?(13) and 55.92?(13)°, respectively]. The phenyl ring is twisted out of the plane of the central residue [C(q)-N-C(ph)-C(ph) = -146.20?(12) and -144.15?(12)°, respectively; q = quaternary and ph = phen-yl]. The independent mol-ecules are linked into a dimeric aggregate by N-H?S hydrogen bonds and an eight-membered thio-amide {?H-N-C=S}(2) synthon.

SUBMITTER: Sudkaow P 

PROVIDER: S-EPMC3379354 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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O-Propyl N-phenyl-thio-carbamate.

Sudkaow Panyapon P   Yeo Chien Ing CI   Ng Seik Weng SW   Tiekink Edward R T ER  

Acta crystallographica. Section E, Structure reports online 20120519 Pt 6

Two independent mol-ecules comprise the asymmetric unit in the title thio-carbamide derivative, C(10)H(13)NOS. These differ in the relative orientations of terminal ethyl groups [C-C-C-O torsion angles = -66.95 (13) and 55.92 (13)°, respectively]. The phenyl ring is twisted out of the plane of the central residue [C(q)-N-C(ph)-C(ph) = -146.20 (12) and -144.15 (12)°, respectively; q = quaternary and ph = phen-yl]. The independent mol-ecules are linked into a dimeric aggregate by N-H⋯S hydrogen bo  ...[more]

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