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P-[N-(Diphenyl-phospho-rothio-yl)iso-propyl-amino]-N-isopropyl-P-phenyl-thio-phosphinic amide.

ABSTRACT: The title compound, C(24)H(30)N(2)P(2)S(2), was obtained by the reaction of Ph(2)PN(iPr)P(Ph)N(iPr)H with elemental sulfur in tetra-hydro-furan. In the solid state, intra-molecular N-H?S hydrogen bonding influences the mol-ecular conformation; a P-N-P-N torsion angle of 2.28?(9)° is observed. The two phenyl rings attached to one P atom form a dihedral angle of 74.02?(4)°.

SUBMITTER: Peulecke N

PROVIDER: S-EPMC2977763 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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P-[N-(Diphenyl-phospho-rothio-yl)iso-propyl-amino]-N-isopropyl-P-phenyl-thio-phosphinic amide.

Peulecke Normen N Aluri Bhaskar R BR Wöhl Anina A Spannenberg Anke A Al-Hazmi Mohammed H MH

Acta crystallographica. Section E, Structure reports online 20090422 Pt 5

The title compound, C(24)H(30)N(2)P(2)S(2), was obtained by the reaction of Ph(2)PN(iPr)P(Ph)N(iPr)H with elemental sulfur in tetra-hydro-furan. In the solid state, intra-molecular N-H⋯S hydrogen bonding influences the mol-ecular conformation; a P-N-P-N torsion angle of 2.28 (9)° is observed. The two phenyl rings attached to one P atom form a dihedral angle of 74.02 (4)°. ...[more]

PMID: 21583899

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