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2-Chloro-N-(2-methyl-phen-yl)benzamide.

ABSTRACT: In the title compound, C(14)H(12)ClNO, the two aromatic rings are almost coplanar, making a dihedral angle of 4.08?(18)°. In the crystal, N-H?O hydrogen bonds link the mol-ecules into infinite chains running along the a axis.

SUBMITTER: Rodrigues VZ

PROVIDER: S-EPMC3379489 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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2-Chloro-N-(2-methyl-phen-yl)benzamide.

Rodrigues Vinola Z VZ Gowda B Thimme BT Sivý Július J Vrábel Viktor V Kožíšek Jozef J

Acta crystallographica. Section E, Structure reports online 20120531 Pt 6

In the title compound, C(14)H(12)ClNO, the two aromatic rings are almost coplanar, making a dihedral angle of 4.08 (18)°. In the crystal, N-H⋯O hydrogen bonds link the mol-ecules into infinite chains running along the a axis. ...[more]

PMID: 22719687

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N-(4-Chloro-phen-yl)-2-methyl-benzamide.

Project description:In the structure of the title compound, C(14)H(12)ClNO, the N-H and C=O bonds are trans to each other. Furthermore, the C=O bond is syn to the ortho-methyl group in the benzoyl ring, similar to what is observed in 2-methyl-N-(4-methyl-phen-yl)benzamide and 2-methyl-N-phenyl-benzamide. The amide linkage (-NHCO-) makes dihedral angles of 36.9?(7) and 46.4?(5)° with the aniline and benzoyl rings, respectively, while the dihedral angle between the benzoyl and aniline rings is 83.1?(1)°. In the crystal structure, mol-ecules form chains running along the b axis through N-H?O hydrogen bonds.

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Project description:In the title compound, C(14)H(12)ClNO, the aromatic rings make a dihedral angle of 59.25?(5)°. The methyl group is disordered over two equally occupied positions. In the crystal, N-H?O hydrogen bonds link the mol-ecules into infinite C(4) chains running along the a axis.

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N-(3-Chloro-phen-yl)-2-methyl-benzamide.

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3-Chloro-N-(3-methyl-phen-yl)benzamide.

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3-Chloro-N-(2-methyl-phen-yl)benzamide.

Project description:In the mol-ecular structure of the title compound, C(14)H(12)ClNO, the meta-Cl atom in the benzoyl ring is positioned anti to the C=O bond, while the ortho-methyl group in the aniline ring is positioned syn to the N-H bond. The two benzene rings are nearly coplanar [dihedral angle = 3.48 (5)°]. The crystal structure is stabilized by N-H⋯O hydrogen bonds, which link the mol-ecules into chains along the b axis.

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N-(3-Chloro-phen-yl)-3-methyl-benzamide hemihydrate.

Project description:In the title compound, C(14)H(12)ClNO·0.5H(2)O, the N-H bond is in an anti conformation to the C=O bond. The two aromatic rings make a dihedral angle of 49.5?(1)°. The water mol-ecule lies on a twofold rotation axis. In the crystal, inter-molecular N-H?O and O-H?O hydrogen bonds connect the mol-ecules into a three-dimensional network.

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