Ontology highlight
ABSTRACT:
SUBMITTER: Affan MA
PROVIDER: S-EPMC3393180 | biostudies-literature | 2012 Jul
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20120616 Pt 7
Two independent mol-ecules comprise the asymmetric unit in the title compound, [Sn(C₄H₉)(C₁₄H₁₉N₄S)Cl₂]. In each mol-ecule, the Sn(IV) atom exists within a distorted octa-hedral geometry defined by the N,N',S-tridentate mono-deprotonated Schiff base ligand, two mutually trans Cl atoms, and the α-C atom of the n-butyl group; the latter is trans to the azo-N atom. The greatest distortion from the ideal geometry is found in the nominally trans angle formed by the S and pyridyl-N atoms at Sn [151.72 ...[more]