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Chloridodimeth-yl(thio-semi-carbazide)tin(IV) chloride.

ABSTRACT: In the title salt, [Sn(CH(3))(2)Cl(CH(4)N(3)S)]Cl, the Sn(IV) atom is five-coordinated in a distorted trigonal-bipyramidal geometry with two methyl groups and one S atom in the equatorial plane, and one N atom and one Cl atom occupying the apical positions. In the crystal, mol-ecules are linked by inter-molecular N-H?S hydrogen bonds with set graph-motif C(4) along [010]. N-H? Cl hydrogen bonds with graph-set motif D(2) and D(3) (3)(10) link cations and anions.

SUBMITTER: Cortes C L

PROVIDER: S-EPMC3009011 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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Chloridodimeth-yl(thio-semi-carbazide)tin(IV) chloride.

Cortes C Laura L Burgos C Ana E AE Okio Coco K Y A CK

Acta crystallographica. Section E, Structure reports online 20101002 Pt 11

In the title salt, [Sn(CH(3))(2)Cl(CH(4)N(3)S)]Cl, the Sn(IV) atom is five-coordinated in a distorted trigonal-bipyramidal geometry with two methyl groups and one S atom in the equatorial plane, and one N atom and one Cl atom occupying the apical positions. In the crystal, mol-ecules are linked by inter-molecular N-H⋯S hydrogen bonds with set graph-motif C(4) along [010]. N-H⋯ Cl hydrogen bonds with graph-set motif D(2) and D(3) (3)(10) link cations and anions. ...[more]

PMID: 21588798

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