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Cyclo-pentyl-diphen-yl(4-thio-semi-carbazonopenta-noato-κO)tin(IV).

ABSTRACT: The Sn atom in the title compound, [Sn(C(5)H(9))(C(6)H(5))(2)(C(6)H(10)N(3)O(2)S)], exists within a tetra-hedral geometry. The -NH(2) group forms a weak hydrogen bond across a center of inversion to the S atom of an adjacent mol-ecule, as well as another weaker hydrogen (across another center of inversion) to the Sn-bound O atom of another mol-ecule. The hydrogen-bonded layer structure is consolidated by a strong hydrogen bond between the -NH- group and the uncoordinated O atom of a third mol-ecule.

SUBMITTER: Lo KM

PROVIDER: S-EPMC2961090 | biostudies-literature | 2008 Apr

REPOSITORIES: biostudies-literature

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Cyclo-pentyl-diphen-yl(4-thio-semi-carbazonopenta-noato-κO)tin(IV).

Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20080426 Pt 5

The Sn atom in the title compound, [Sn(C(5)H(9))(C(6)H(5))(2)(C(6)H(10)N(3)O(2)S)], exists within a tetra-hedral geometry. The -NH(2) group forms a weak hydrogen bond across a center of inversion to the S atom of an adjacent mol-ecule, as well as another weaker hydrogen (across another center of inversion) to the Sn-bound O atom of another mol-ecule. The hydrogen-bonded layer structure is consolidated by a strong hydrogen bond between the -NH- group and the uncoordinated O atom of a third mol-ec ...[more]

PMID: 21202248

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