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6,6'-Dimethyl-2,2'-bipyridin-1-ium tetra-chloridoaurate(III).

ABSTRACT: In the anion of the title compound, (C(12)H(13)N(2))[AuCl(4)], the Au(III) atom has a square-planar coordination. In the crystal, inter-molecular N-H?Cl and C-H?Cl hydrogen bonds and ?-? contacts between the pyridine rings [centroid-centroid distance = 3.5419?(19)?Å] result in the formation of a supra-molecular structure.

SUBMITTER: Zare Dehnavi M

PROVIDER: S-EPMC3393230 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

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6,6'-Dimethyl-2,2'-bipyridin-1-ium tetra-chloridoaurate(III).

Zare Dehnavi Marzieh M Abedi Anita A

Acta crystallographica. Section E, Structure reports online 20120630 Pt 7

In the anion of the title compound, (C(12)H(13)N(2))[AuCl(4)], the Au(III) atom has a square-planar coordination. In the crystal, inter-molecular N-H⋯Cl and C-H⋯Cl hydrogen bonds and π-π contacts between the pyridine rings [centroid-centroid distance = 3.5419 (19) Å] result in the formation of a supra-molecular structure. ...[more]

PMID: 22807798

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