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{4,4',6,6'-Tetra-chloro-2,2'-[2,2-dimethyl-propane-1,3-diylbis(nitrilo-methanylyl-idene)]}copper(II).

ABSTRACT: In the title Schiff base complex, [Cu(C(19)H(16)Cl(4)N(2)O(2))], the geometry around the Cu(II) atom is distorted square-planar defined by the N(2)O(2) donor atoms of the coordinated ligand. The dihedral angle between the substituted benzene rings is 29.95?(16)°. In the crystal, mol-ecules are linked along the b axis, forming individual dimers through C-H?O inter-actions. The crystal structure is further stabilized by inter-molecular ?-? inter-actions [centroid-centroid distance = 3.6131?(17)?Å].

SUBMITTER: Kargar H

PROVIDER: S-EPMC3274908 | biostudies-other | 2012 Feb

REPOSITORIES: biostudies-other

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{4,4',6,6'-Tetra-chloro-2,2'-[2,2-dimethyl-propane-1,3-diylbis(nitrilo-methanylyl-idene)]}copper(II).

Kargar Hadi H Kia Reza R Abbasian Saeideh S Tahir Muhammad Nawaz MN

Acta crystallographica. Section E, Structure reports online 20120121 Pt 2

In the title Schiff base complex, [Cu(C(19)H(16)Cl(4)N(2)O(2))], the geometry around the Cu(II) atom is distorted square-planar defined by the N(2)O(2) donor atoms of the coordinated ligand. The dihedral angle between the substituted benzene rings is 29.95 (16)°. In the crystal, mol-ecules are linked along the b axis, forming individual dimers through C-H⋯O inter-actions. The crystal structure is further stabilized by inter-molecular π-π inter-actions [centroid-centroid distance = 3.6131 (17) Å] ...[more]

PMID: 22346855

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