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(4E)-N-[(2-Bromo-phen-yl)meth-oxy]-1,3-dimethyl-2,6-diphenyl-piperidin-4-imine.

ABSTRACT: In the title compound, C(26)H(27)BrN(2)O, the piperidine ring has a chair conformation and all ring substituents occupy equatorial positions, apart from the double-bonded N atom, which occupies a bis-ectional position. The dihedral angle formed between the phenyl rings is 61.18?(19)°, and the phenyl rings form dihedral angles of 49.78?(19) and 69.2?(18)° with the bromo-benzene ring. The latter is coplanar with the meth-oxy(methyl-idene)amine fragment [N-O-C-C torsion angle = -171.7?(2)°]. Linear supra-molecular chains, approximately along [112], sustained by C-H?? inter-actions, feature in the crystal packing.

SUBMITTER: Ramalingan C 

PROVIDER: S-EPMC3394050 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

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(4E)-N-[(2-Bromo-phen-yl)meth-oxy]-1,3-dimethyl-2,6-diphenyl-piperidin-4-imine.

Ramalingan Chennan C   Ng Seik Weng SW   Tiekink Edward R T ER  

Acta crystallographica. Section E, Structure reports online 20120630 Pt 7

In the title compound, C(26)H(27)BrN(2)O, the piperidine ring has a chair conformation and all ring substituents occupy equatorial positions, apart from the double-bonded N atom, which occupies a bis-ectional position. The dihedral angle formed between the phenyl rings is 61.18 (19)°, and the phenyl rings form dihedral angles of 49.78 (19) and 69.2 (18)° with the bromo-benzene ring. The latter is coplanar with the meth-oxy(methyl-idene)amine fragment [N-O-C-C torsion angle = -171.7 (2)°]. Linear  ...[more]

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