Unknown

Dataset Information

0

4,6-Dichloro-2-{[(E)-(3-{[(E)-3,5-dichloro-2-hy-droxy-benzyl-idene]amino}-2,2-dimethyl-prop-yl)imino]-meth-yl}phenol.


ABSTRACT: In the title compound, C(19)H(18)Cl(4)N(2)O(2), a potential tetra-dentate Schiff base ligand, the dihedral angle between the two benzene rings is 48.01?(10)°. The configuration about the two C=N bonds is E and two intra-molecular O-H?N hydrogen bonds make S(6) ring motifs. In the crystal, mol-ecules are linked along the b axis via inter-molecular C-H?Cl inter-actions. The crystal structure is further stabilized by an inter-molecular ?-? inter-action [centroid-centroid distance = 3.5744?(12)?Å].

SUBMITTER: Kargar H 

PROVIDER: S-EPMC3254485 | biostudies-other | 2012 Jan

REPOSITORIES: biostudies-other

altmetric image

Publications

4,6-Dichloro-2-{[(E)-(3-{[(E)-3,5-dichloro-2-hy-droxy-benzyl-idene]amino}-2,2-dimethyl-prop-yl)imino]-meth-yl}phenol.

Kargar Hadi H   Kia Reza R   Abbasian Saeideh S   Tahir Muhammad Nawaz MN  

Acta crystallographica. Section E, Structure reports online 20111217 Pt 1


In the title compound, C(19)H(18)Cl(4)N(2)O(2), a potential tetra-dentate Schiff base ligand, the dihedral angle between the two benzene rings is 48.01 (10)°. The configuration about the two C=N bonds is E and two intra-molecular O-H⋯N hydrogen bonds make S(6) ring motifs. In the crystal, mol-ecules are linked along the b axis via inter-molecular C-H⋯Cl inter-actions. The crystal structure is further stabilized by an inter-molecular π-π inter-action [centroid-centroid distance = 3.5744 (12) Å]. ...[more]

Similar Datasets

| S-EPMC3297293 | biostudies-literature
| S-EPMC3394034 | biostudies-literature
| S-EPMC3379294 | biostudies-literature
| S-EPMC3569760 | biostudies-literature
| S-EPMC3414953 | biostudies-literature
| S-EPMC3394053 | biostudies-literature
| S-EPMC3379400 | biostudies-literature
| S-EPMC3588739 | biostudies-literature
| S-EPMC3050403 | biostudies-literature
| S-EPMC3007216 | biostudies-literature