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(R(P))-5-Methyl-2-(propan-2-yl)cyclo-hexyl phen-yl{phen-yl[(1-phenyl-eth-yl)amino]-meth-yl}phosphinate.

ABSTRACT: In the title compound, C(31)H(40)NO(2)P, the P atom has a distorted tetra-hedral stereochemistry [bond-angle range about P = 103.33?(6)-115.24?(15)°] and has R(P) chirality, which was confirmed crystallographically. The dihedral angles between the P-bonded phenyl ring and the other two phenyl rings are 40.4?(3) and 12.2?(2)°. In the crystal, a C-H?O inter-action links mol-ecules into chains which extend along [100].

SUBMITTER: Yang M 

PROVIDER: S-EPMC3414267 | biostudies-literature | 2012 Aug

REPOSITORIES: biostudies-literature

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(R(P))-5-Methyl-2-(propan-2-yl)cyclo-hexyl phen-yl{phen-yl[(1-phenyl-eth-yl)amino]-meth-yl}phosphinate.

Yang Meng M   Sun Yong-Ming YM   Hou Qing-Gao QG   Zhao Chang-Qiu CQ  

Acta crystallographica. Section E, Structure reports online 20120704 Pt 8

In the title compound, C(31)H(40)NO(2)P, the P atom has a distorted tetra-hedral stereochemistry [bond-angle range about P = 103.33 (6)-115.24 (15)°] and has R(P) chirality, which was confirmed crystallographically. The dihedral angles between the P-bonded phenyl ring and the other two phenyl rings are 40.4 (3) and 12.2 (2)°. In the crystal, a C-H⋯O inter-action links mol-ecules into chains which extend along [100]. ...[more]

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