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2-(2-Meth-oxy-phen-yl)-1H-isoindole-1,3(2H)-dione.

ABSTRACT: In the title compound, C(15)H(11)NO(3), the dihedral angle between the meth-oxy-benzene and isoindole ring systems is 70.21?(3)°. The meth-oxy C atom is close to being coplanar with its attached ring [deviation = 0.133?(2)?Å] and is oriented away from the isoindole moiety. In the crystal, inversion dimers linked by pairs of C-H?O hydrogen bonds generate R(2) (2)(10) loops. Further C-H?O inter-actions lead to (010) infinite sheets and weak aromatic ?-? stacking [centroid-centroid separations = 3.6990?(10) and 3.7217?(10)?Å] is also observed.

SUBMITTER: Tahir MN

PROVIDER: S-EPMC3415027 | biostudies-literature | 2012 Aug

REPOSITORIES: biostudies-literature

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2-(2-Meth-oxy-phen-yl)-1H-isoindole-1,3(2H)-dione.

Tahir M Nawaz MN Sirajuddin Muhammad M Ali Saqib S Munawar Khurram Shahzad KS

Acta crystallographica. Section E, Structure reports online 20120728 Pt 8

In the title compound, C(15)H(11)NO(3), the dihedral angle between the meth-oxy-benzene and isoindole ring systems is 70.21 (3)°. The meth-oxy C atom is close to being coplanar with its attached ring [deviation = 0.133 (2) Å] and is oriented away from the isoindole moiety. In the crystal, inversion dimers linked by pairs of C-H⋯O hydrogen bonds generate R(2) (2)(10) loops. Further C-H⋯O inter-actions lead to (010) infinite sheets and weak aromatic π-π stacking [centroid-centroid separations = 3. ...[more]

PMID: 22905014

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