Ontology highlight
ABSTRACT:
SUBMITTER: Joshi-Pangu A
PROVIDER: S-EPMC3432578 | biostudies-literature | 2012 Aug
REPOSITORIES: biostudies-literature
The Journal of organic chemistry 20120723 15
A mild Pd-catalyzed process for the borylation of alkyl bromides has been developed using bis(pinacolato)diboron as a boron source. This process accommodates the use of a wide range of functional groups on the alkyl bromide substrate. Primary bromides react with complete selectivity in the presence of a secondary bromide. The generality of this approach is demonstrated by its extension to the use of alkyl iodides and alkyl tosylates, as well as borylation reactions employing bis(neopentyl glycol ...[more]