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Bis(di-2-pyridyl-amine-?(2)N(2),N(2'))palladium(II) bis-(thio-cyanate).

ABSTRACT: The Pd(II) atom of the title salt, [Pd(C(10)H(9)N(3))(2)](NCS)(2), lies on a center of inversion and exists in a square-planar environment defined by the four pyridine N atoms derived from the two chelating di-2-pyridyl-amine (dpa) ligands. The chelate ring displays a boat conformation with a dihedral angle between the pyridine rings of 43.0?(1)°. Adjacent thio-cyanate ions are linked to the cations by N-H?N hydrogen bonds.

SUBMITTER: Ha K

PROVIDER: S-EPMC3435575 | biostudies-literature | 2012 Sep

REPOSITORIES: biostudies-literature

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Bis(di-2-pyridyl-amine-κ(2)N(2),N(2'))palladium(II) bis-(thio-cyanate).

Ha Kwang K

Acta crystallographica. Section E, Structure reports online 20120804 Pt 9

The Pd(II) atom of the title salt, [Pd(C(10)H(9)N(3))(2)](NCS)(2), lies on a center of inversion and exists in a square-planar environment defined by the four pyridine N atoms derived from the two chelating di-2-pyridyl-amine (dpa) ligands. The chelate ring displays a boat conformation with a dihedral angle between the pyridine rings of 43.0 (1)°. Adjacent thio-cyanate ions are linked to the cations by N-H⋯N hydrogen bonds. ...[more]

PMID: 22969448

Similar Datasets

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cis-(Di-2-pyridyl-amine-?(2)N(2),N(2'))bis-(thio-cyanato-?S)platinum(II).

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Project description:The whole mol-ecule of the title complex, [Pd(C15H21N2S2)2], is generated by twofold rotational symmetry. The palladium(II) atom exhibits a square-planar coordination geometry, and is located on the crystallographic twofold axis that induces a cis configuration of the N,S chelating ligands. In the crystal, mol-ecules stack along the c-axis direction and there are no significant inter-molecular inter-actions present. The structure was refined as an inversion twin with a final BASF parameter of 0.34 (2).

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