Browse
Submit Data
Databases
API
Help

Dataset Information

27 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Cis-Aqua-bis-(di-2-pyridyl-amine-?N,N')iodidomanganese(II) iodide.

ABSTRACT: The asymmetric unit of the title compound, [MnI(C(10)H(9)N(3))(2)(H(2)O)]I, contains a cationic Mn(II) complex and an I(-) anion. In the complex, the Mn(II) ion is six-coordinated in a considerably distorted cis-N(4)IO octa-hedral environment defined by four N atoms of the two chelating di-2-pyridyl-amine (dpa) ligands, one I(-) anion and one O atom of a water ligand. As a result of the different trans effects of the I, N and O atoms, the Mn-N bond trans to the I atom is slightly longer than the Mn-N bond trans to the N or O atoms. The dpa ligands are not planar, with dihedral angles between the two pyridine rings of 26.2?(4) and 26.5?(4)°. The complex cations are stacked in columns along the a axis and are linked to the anions by inter-molecular O-H?I and N-H?I hydrogen bonds.

SUBMITTER: Ha K

PROVIDER: S-EPMC3238658 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

cis-Aqua-bis-(di-2-pyridyl-amine-κN,N')iodidomanganese(II) iodide.

Ha Kwang K

Acta crystallographica. Section E, Structure reports online 20111112 Pt 12

The asymmetric unit of the title compound, [MnI(C(10)H(9)N(3))(2)(H(2)O)]I, contains a cationic Mn(II) complex and an I(-) anion. In the complex, the Mn(II) ion is six-coordinated in a considerably distorted cis-N(4)IO octa-hedral environment defined by four N atoms of the two chelating di-2-pyridyl-amine (dpa) ligands, one I(-) anion and one O atom of a water ligand. As a result of the different trans effects of the I, N and O atoms, the Mn-N bond trans to the I atom is slightly longer than the ...[more]

PMID: 22199549

Similar Datasets

cis-Aqua-bromidobis(di-2-pyridyl-amine-?N,N')manganese(II) bromide.

Project description:In the title compound, [MnBr(C(10)H(9)N(3))(2)(H(2)O)]Br, the Mn(II) ion is six-coordinated in a considerably distorted cis-N(4)BrO octa-hedral environment defined by four N atoms of two chelating di-2-pyridyl-amine (dpa) ligands, one Br(-) anion and one O atom of a water ligand. As a result of the different trans effects of Br, N and O atoms, the Mn-N bond trans to the Br atom is slightly longer than the Mn-N bond trans to the N or O atoms. In the crystal, the dpa ligands are not planar, the dihedral angles between the two pyridine rings being 29.2?(4) and 28.2?(3)°. The complex cations and the Br(-) anions are linked by inter-molecular O-H?Br and N-H?Br hydrogen bonds. Inter-molecular ?-? inter-actions are present between the pyridine rings, with a centroid-centroid distance of 3.793?(4)?Å.

| S-EPMC3238689 | biostudies-literature

Aqua-dicrotonato(di-2-pyridyl-amine)cobalt(II).

Project description:The Co atom in the title complex, [Co(CH(3)CHCHCOO)(2)(C(10)H(9)N(3))(H(2)O)], has a distorted recta-ngular-pyramidal geometry formed by the chelating dipyridylamine ligand, and two O atoms of monodentate carboxyl-ate groups of two different crotonate anions and a water molecule. The complex forms a three-dimensional supra-molecular network via inter-molecular O-H?O, N-H?O and C-H?O hydrogen-bonding contacts.

| S-EPMC2961059 | biostudies-literature

cis-Aqua-bis-(2,2'-bipyrimidine-?N,N)iodidomanganese(II) iodide monohydrate.

Project description:The asymmetric unit of the title compound, [MnI(C(8)H(6)N(4))(2)(H(2)O)]I·H(2)O, consists of a cationic Mn(II) complex, an I(-) anion and a solvent water mol-ecule. In the complex, the Mn(II) ion is six-coordinated in a distorted octa-hedral environment defined by four N atoms of the two chelating 2,2'-bipyrimidine (bpym) ligands, one I(-) anion and one O atom of a water ligand. The dihedral angle between the least-squares planes of the two bpym ligands [maximum deviation = 0.092?(7)?Å] is 79.9?(1)°. In the crystal, the complex, anion and solvent water mol-ecule are linked by inter-molecular O-H?O, O-H?I and O-H?N hydrogen bonds.

| S-EPMC3201340 | biostudies-literature

cis-Aqua-bis-(2,2'-bipyrimidine-?N,N)iodidomanganese(II) iodide dihydrate.

Project description:The asymmetric unit of the title compound, [MnI(C(8)H(6)N(4))(2)(H(2)O)]I·2H(2)O, contains a cationic Mn(II) complex, an I(-) anion and two solvent water mol-ecules. In the complex, the Mn(II) ion is six-coordinated in a considerably distorted octa-hedral environment defined by four N atoms of the two chelating 2,2'-bipyrimidine (bpym) ligands, one I(-) anion and one O atom of a water ligand. As a result of the different trans effects of the I and O atoms, the Mn-N bond trans to the I atom is slightly longer than the Mn-N bond trans to the O atom. The dihedral angle between the least-squares planes of the two bpym ligands [maximum deviation = 0.088?(4)?Å] is 76.48?(6)°. In the crystal, the complex cation, the anion and the solvent water mol-ecules are linked by inter-molecular O-H?O, O-H?I and O-H?N hydrogen bonds.

| S-EPMC3201460 | biostudies-literature

Bis(di-2-pyridyl-amine-?N,N')bis-(thio-cyanato-?N)nickel(II).

Project description:The mononuclear neutral title complex, [Ni(NCS)(2)(C(10)H(9)N(3))(2)], shows a cis-octa-hedral geometry around the Ni(II) ion, formed by two chelating di-2-pyridyl-amine (Hdpa) ligands and two thio-cyanate anions. Both amine H atoms are involved in N-H?S hydrogen bonding, resulting in the formation of layers of inter-linked mol-ecules parallel to the ab plane, which are further held together by weak ?-? inter-actions between adjacent complexes, involving one ring of each dipyridyl-amine unit [centroid-centroid distance = 3.777?(4)?Å], forming a three-dimensional assembly.

| S-EPMC3238757 | biostudies-literature

Di-aqua-bis-(ethyl-enedi-amine-?(2) N,N')copper(II) bis-(sulfamerazinate).

Project description:The asymmetric unit of the title compound, [Cu(C2H8N2)2(H2O)2](C11H11N4O2S)2, contains one sulfamerazinate anion in a general position and one half-cation that is located on a center of inversion. The Cu(II) cation shows a strong Jahn-Teller distortion. It is coordinated by four N atoms of two ethyl-enedi-amine ligands in the basal plane and two O atoms at much longer distances in the axial positions in a bipyramidal coordination. In the crystal, the building blocks are connected by N-H?N, O-H?N, N-H?O and O-H?O hydrogen bonding into a two-dimensional network parallel to (001).

| S-EPMC4051046 | biostudies-literature

cis-Dichloridobis(di-2-pyridyl-amine-?N,N')manganese(II).

Project description:In the title complex, [MnCl(2)(C(10)H(9)N(3))(2)], the Mn(II) ion is six-coordinated in a considerably distorted cis-N(4)Cl(2) octa-hedral environment defined by four N atoms of two chelating di-2-pyridyl-amine (dpa) ligands and two Cl(-) anions. In the crystal, the dpa ligands are not planar, the dihedral angles between the two pyridine rings being 29.3?(2) and 30.9?(2)°. The complex mol-ecules are stacked in columns along the c axis and are connected by inter-molecular N-H?Cl hydrogen bonds, forming a three-dimensional network. Weak inter- and intra-molecular ?-? inter-actions are present between the pyridine rings, the shortest centroid-centroid distance being 4.406?(3)?Å.

| S-EPMC3254314 | biostudies-other

Tetra-aqua-bis(3,5-di-4-pyridyl-1,2,4-triazolato-?N)nickel(II) dihydrate.

Project description:The Ni(II) atom in the title compound, [Ni(C(12)H(8)N(5))(2)(H(2)O)(4)]·2H(2)O, lies on a center of inversion and is coordinated by the N atoms of two 3,5-di-4-pyridine-1,2,4-triazolate ligands and by four water O atoms in a slightly distorted octa-hedral geometry. The coordinated and uncoordinated water mol-ecules inter-act with the N-heterocycles through O-H?N and O-H?O hydrogen bonds, generating a three-dimensional supra-molecular architecture.

| S-EPMC2977209 | biostudies-literature

Tetra-aqua-bis(3,5-di-4-pyridyl-1H-1,2,4-triazolido)cadmium(II) dihydrate.

Project description:In the title compound, [Cd(C(12)H(8)N(5))(2)(H(2)O)(4)]·2H(2)O, the Cd(II) atom is located on an inversion center and is coordinated by the two N atoms [Cd-N = 2.278?(2)?Å] and four O atoms [Cd-O = 2.304?(2)-2.322?(2)?Å] in a distorted octa-hedral geometry. Inter-molecular O-H?O and O-H?N hydrogen bonds link the complex into a three-dimensional supra-molecular framework.

| S-EPMC2977399 | biostudies-literature

Tetra-aqua-bis(3,5-di-4-pyridyl-1,2,4-triazolato-?N)cobalt(II) dihydrate.

Project description:The Co(II) atom in the title compound, [Co(C(12)H(8)N(5))(2)(H(2)O)(4)]·2H(2)O, lies on a center of inversion and is bonded to two N-heterocycles and to four water mol-ecules in a slightly distorted octahedral coordination. The coordinated and lattice water mol-ecules inter-act with the N-heterocycles through O-H?N hydrogen bonds, generating a three-dimensional supra-molecular architecture.

| S-EPMC2977553 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data