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Dichloridobis{1-[(2-methyl-benzimidazol-1-yl-?N(3))meth-yl]benzotriazole}zinc.

ABSTRACT: The title mononuclear Zn(II) complex, [ZnCl(2)(C(15)H(13)N(5))(2)], is isotypic with the previously reported Hg(II) complex. The Zn(II) atom is located on a twofold rotation axis and has a distorted tetra-hedral environment of two Cl atoms and two N atoms from two heterocyclic ligands. In the crystal, complex mol-ecules are extended by inter-molecular ?-? inter-actions [centroid-centroid distance = 3.792?(2)?Å] into a three-dimensional supra-molecular network.

SUBMITTER: Song L

PROVIDER: S-EPMC3435601 | biostudies-literature | 2012 Sep

REPOSITORIES: biostudies-literature

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Dichloridobis{1-[(2-methyl-benzimidazol-1-yl-κN(3))meth-yl]benzotriazole}zinc.

Song Lianqing L Zhao Meihong M Cui Guoshi G Gao Jianghua J Lin Lin L

Acta crystallographica. Section E, Structure reports online 20120815 Pt 9

The title mononuclear Zn(II) complex, [ZnCl(2)(C(15)H(13)N(5))(2)], is isotypic with the previously reported Hg(II) complex. The Zn(II) atom is located on a twofold rotation axis and has a distorted tetra-hedral environment of two Cl atoms and two N atoms from two heterocyclic ligands. In the crystal, complex mol-ecules are extended by inter-molecular π-π inter-actions [centroid-centroid distance = 3.792 (2) Å] into a three-dimensional supra-molecular network. ...[more]

PMID: 22969474

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