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Dichloridobis[4-(1H-pyrazol-3-yl)pyridine-?N]zinc.

ABSTRACT: In the title compound, [ZnCl(2)(C(8)H(7)N(3))(2)], the Zn(II) cation is coordinated by two Cl(-) anions and two 4-(1H-pyrazol-3-yl)pyridine ligands in a distorted tetra-hedral geometry. In the two 4-(1H-pyrazol-3-yl)pyridine ligands, the dihedral angles between the pyrazole and pyridine rings are 3.3?(3) and 13.3?(3)°. Inter-molecular N-H?N and N-H?Cl hydrogen bonding is present in the crystal structure.

SUBMITTER: Tan ZD

PROVIDER: S-EPMC3201423 | biostudies-literature | 2011 Oct

REPOSITORIES: biostudies-literature

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Dichloridobis[4-(1H-pyrazol-3-yl)pyridine-κN]zinc.

Tan Zheng-De ZD Tan Feng-Jiao FJ Tan Bo B Zhang Cheng-Ming CM

Acta crystallographica. Section E, Structure reports online 20110930 Pt 10

In the title compound, [ZnCl(2)(C(8)H(7)N(3))(2)], the Zn(II) cation is coordinated by two Cl(-) anions and two 4-(1H-pyrazol-3-yl)pyridine ligands in a distorted tetra-hedral geometry. In the two 4-(1H-pyrazol-3-yl)pyridine ligands, the dihedral angles between the pyrazole and pyridine rings are 3.3 (3) and 13.3 (3)°. Inter-molecular N-H⋯N and N-H⋯Cl hydrogen bonding is present in the crystal structure. ...[more]

PMID: 22065794

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