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Trichlorido(4,4'-dimethyl-2,2'-bipyridine-?(2)N,N')(methanol-?O)indium(III) methanol monosolvate.


ABSTRACT: In the title compound, [InCl(3)(C(12)H(12)N(2))(CH(3)OH)]·CH(3)OH, the In(III) atom is six-coordinated in a distorted octa-hedral geometry by two N atoms from a chelating 4,4'-dimethyl-2,2'-bipyridine ligand, one O atom from a methanol mol-ecule and three Cl atoms. In the crystal, inter-molecular O-H?O and O-H?Cl hydrogen bonds link the complex and solvent methanol mol-ecules. Intra-molecular C-H?Cl hydrogen bonds are also present in the complex.

SUBMITTER: Shirvan SA 

PROVIDER: S-EPMC3435608 | biostudies-literature | 2012 Sep

REPOSITORIES: biostudies-literature

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Trichlorido(4,4'-dimethyl-2,2'-bipyridine-κ(2)N,N')(methanol-κO)indium(III) methanol monosolvate.

Shirvan Sadif A SA   Haydari Dezfuli Sara S  

Acta crystallographica. Section E, Structure reports online 20120823 Pt 9


In the title compound, [InCl(3)(C(12)H(12)N(2))(CH(3)OH)]·CH(3)OH, the In(III) atom is six-coordinated in a distorted octa-hedral geometry by two N atoms from a chelating 4,4'-dimethyl-2,2'-bipyridine ligand, one O atom from a methanol mol-ecule and three Cl atoms. In the crystal, inter-molecular O-H⋯O and O-H⋯Cl hydrogen bonds link the complex and solvent methanol mol-ecules. Intra-molecular C-H⋯Cl hydrogen bonds are also present in the complex. ...[more]

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