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Trichlorido(5,5'-dimethyl-2,2'-bipyridine-?N,N')(methanol-?O)indium(III).

ABSTRACT: In the mol-ecule of the title compound, [InCl(3)(C(12)H(12)N(2))(CH(4)O)], the In(III) atom is six-coordinated in a distorted octa-hedral configuration by two N atoms from the chelating 5,5'-dimethyl-2,2'-bipyridine ligand, one O atom from a methanol molecule and three Cl atoms. In the crystal structure, inter-molecular O-H?Cl hydrogen bonds link the mol-ecules into chains parallel to [001].

SUBMITTER: Kalateh K

PROVIDER: S-EPMC2959790 | biostudies-literature | 2008 Oct

REPOSITORIES: biostudies-literature

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Trichlorido(5,5'-dimethyl-2,2'-bipyridine-κN,N')(methanol-κO)indium(III).

Kalateh Khadijeh K Ahmadi Roya R Ebadi Amin A Amani Vahid V Khavasi Hamid Reza HR

Acta crystallographica. Section E, Structure reports online 20081004 Pt 11

In the mol-ecule of the title compound, [InCl(3)(C(12)H(12)N(2))(CH(4)O)], the In(III) atom is six-coordinated in a distorted octa-hedral configuration by two N atoms from the chelating 5,5'-dimethyl-2,2'-bipyridine ligand, one O atom from a methanol molecule and three Cl atoms. In the crystal structure, inter-molecular O-H⋯Cl hydrogen bonds link the mol-ecules into chains parallel to [001]. ...[more]

PMID: 21580816

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Trichlorido(4,4'-dimethyl-2,2'-bipyridine-κN,N')(dimethyl sulfoxide-κO)indium(III).

Project description:In the mol-ecule of the title compound, [InCl(3)(C(12)H(12)N(2))(C(2)H(6)OS)], the In(III) atom is six-coordinated in a distorted octa-hedral configuration by two N atoms from the chelating 4,4'-dimethyl-2,2'-bipyridine ligand, one O atom from dimethyl sulfoxide and three Cl atoms. In the crystal structure, inter-molecular C-H⋯Cl hydrogen bonds link the mol-ecules into centrosymmetric dimers.

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Trichlorido(4,4'-dimethyl-2,2'-bipyridine-κ(2)N,N')(methanol-κO)indium(III) methanol monosolvate.

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Project description:The asymmetric unit of the title compound, [InCl3(C12H12N2)(C3H7NO)]·0.5H2O, contains two independent In(III) complex mol-ecules with similar structures and one lattice water mol-ecule. In each complex mol-ecule, the In(III) atom is six-coordinated in a distorted octa-hedral geometry, formed by two N atoms from the chelating 5,5'-dimethyl-2,2'-bipyridine ligand, one O atom from a dimethyl-formamide and three facial Cl atoms. In the crystal, the lattice water mol-ecule is linked to the complex mol-ecules via O-H?Cl hydrogen bonds. Further weak C-H?Cl and C-H?O hydrogen bonds result in the formation of a three-dimensional structure.

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Di-μ-hydroxido-κO:O-μ-trifluoro-methane-sulfonato-κO:O'-bis-[(5,5'-dimethyl-2,2-bipyridine-κN,N')(η-penta-methyl-cyclo-penta-dien-yl)ytterbium(III)] tetra-phenyl-borate 5,5'-dimethyl-2,2-bipyridine.

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Project description:The asymmetric unit of the title compound, C(12)H(12)N(2), contains two half-mol-ecules related by an inversion center, the planes of their pyridine rings being oriented at a dihedral angle of 69.62?(4)°. In the crystal structure, a ?-? contact between the pyridine rings [centroid-centroid distance = 3.895?(3)?Å] may stabilize the structure. A weak C-H?? inter-action is also found.

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Project description:In the structure of the title complex, [Cu(C(7)H(5)O(2))(OH)(C(12)H(12)N(2))(C(7)H(6)O(2))]·H(2)O, the Cu(II) ion is penta-coordinated in a tetra-gonal-pyramidal geometry with one O atom of a hydroxide group, one O atom of a benzoate anion and two N atoms of a 4,4'-dimethyl-2,2'-bipyridine ligand occupying the basal plane, and one O atom of a benzoic acid mol-ecule located at the apical site. The title complex was refined with a metal-coordinated OH group and a 'free' benzoic acid molecule, although it can be assumed that the proton is delocalized between the OH and the COOH group. The uncoordinated water mol-ecule is equally disordered over two positions. The structure displays O-H⋯O hydrogen bonding.

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Potassium (2,2'-bipyridine-κN,N')bis-(carbonato-κO,O')cobaltate(III) dihydrate.

Project description:In the title compound, K[Co(CO(3))(2)(C(10)H(8)N(2))]·2H(2)O, the Co(III) atom is coordinated by two bipyridine N atoms and four O atoms from two bidentate chelating carbonate anions, and thus adopts a distorted octa-hedral N(2)O(4) environment. The [Co(bipy)(CO(3))(2)](-) (bipy is 2,2'-bipyridine) -units are stacked along [100] via π-π stacking inter-actions, with inter-planar distances between the bipyridine rings of 3.36 (4) and 3.44 (6) Å, forming chains. Classical O-H⋯O hydrogen-bonding inter-actions link the chains, forming channels along (100) in which the K(+) ions reside and leading to a three-dimensional supra-molecular architecture.

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(5,5'-Dimethyl-2,2'-bipyridine)-iodido-trimethyl-platinum(IV).

Project description:In the title compound, [Pt(CH(3))(3)I(C(12)H(12)N(2))], the Pt(IV) atom is six-coordinated in a slightly distorted octa-hedral configuration with one CH(3) group and the I atom forming a near perpendicular axis relative to the square plane formed by the bipyridine ligand and the two remaining CH(3) groups. The CH(3) group trans to the I atom has a slightly elongated bond to Pt compared to the other CH(3) groups, indicating a difference in trans influence between iodine and the bipyridine ligand.

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(5,5'-Dimethyl-2,2'-bipyridine-?N,N')diiodidomercury(II).

Project description:In the mol-ecule of the title compound, [HgI(2)(C(12)H(12)N(2))], the Hg(II) atom is four-coordinated in a distorted tetra-hedral configuration by two N atoms from 5,5'-dimethyl-2,2'-bipyridine and two I atoms. There is a ?-? contact between pyridine rings of adjacent molecules [centroid-centroid distance = 3.723?(5)?Å].

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