Unknown

Dataset Information

0

Catena-Poly[[[diaqua-(1,10-phenanthroline-?(2)N,N')zinc]-?-4,4'-bipyridine-?(2)N:N'] dinitrate 4,4'-bipyridine hemisolvate monohydrate].

ABSTRACT: In the title compound, [Zn(C(10)H(8)N(2))(C(12)H(8)N(2))(H(2)O)(2)](NO(3))(2)·0.5C(10)H(8)N(2)·H(2)O, the Zn(II) atom is coordinated in a distorted octa-hedral geometry by two N atoms from two 4,4'-bipyridine (4,4'-bipy) ligands, two N atoms from a chelating 1,10-phenanthroline ligand and two O atoms from two mutually cis water mol-ecules. The 4,4'-bipy ligands bridge the Zn(II) atoms into a chain structure along [100]. The uncoordinated 4,4'-bipy mol-ecule lies on an inversion center. O-H?O and O-H?N hydrogen bonds connect the cationic chains, the nitrate anions, the uncoordinated 4,4'-bipy mol-ecules and the water mol-ecules into tow-dimensional networks.

SUBMITTER: Xu S 

PROVIDER: S-EPMC3435629 | biostudies-literature | 2012 Sep

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

catena-Poly[[[diaqua-(1,10-phenanthroline-κ(2)N,N')zinc]-μ-4,4'-bipyridine-κ(2)N:N'] dinitrate 4,4'-bipyridine hemisolvate monohydrate].

Xu Shan S   Dai Yong-Cheng YC   Qiu Qi-Ming QM   Jin Qiong-Hua QH   Zhang Cun-Lin CL  

Acta crystallographica. Section E, Structure reports online 20120831 Pt 9

In the title compound, [Zn(C(10)H(8)N(2))(C(12)H(8)N(2))(H(2)O)(2)](NO(3))(2)·0.5C(10)H(8)N(2)·H(2)O, the Zn(II) atom is coordinated in a distorted octa-hedral geometry by two N atoms from two 4,4'-bipyridine (4,4'-bipy) ligands, two N atoms from a chelating 1,10-phenanthroline ligand and two O atoms from two mutually cis water mol-ecules. The 4,4'-bipy ligands bridge the Zn(II) atoms into a chain structure along [100]. The uncoordinated 4,4'-bipy mol-ecule lies on an inversion center. O-H⋯O and  ...[more]

Similar Datasets

Unknown catena-Poly[[diaqua-bis(diphenyl-acetato)-zinc(II)]-?-4,4'-bipyridine].
| S-EPMC2968569 | biostudies-literature
Unknown catena-Poly[[[(1,10-phenanthroline)copper(I)]-?-cyanido] ethanol hemisolvate].
| S-EPMC3011795 | biostudies-literature
Unknown catena-Poly[[[bis-(1,10-phenanthroline-?N,N')manganese(II)]-?-2,2'-dithio-dibenzoato-?O,O] methanol hemisolvate monohydrate].
| S-EPMC2970205 | biostudies-literature
Unknown catena-Poly[4,4'-bipyridinium [[diaqua-disulfatocadmium(II)]-?-4,4'-bipyridine-?N:N'] dihydrate].
| S-EPMC2980147 | biostudies-literature
Unknown catena-Poly[[[aqua-(1,10-phenanthroline-?²N,N')zinc]-?-acetyl-ene-dicarboxyl-ato-?²O¹:O²] monohydrate].
| S-EPMC3393169 | biostudies-literature
Unknown catena-Poly[[[aqua-(pyrazino-[2,3-f][1,10]phenanthroline-?N,N)zinc(II)]-?-penta-nedioato] monohydrate].
| S-EPMC3011601 | biostudies-literature
Unknown catena-Poly[[diaqua-bis(thio-cyanato-?N)cobalt(II)]-?-4,4'-bipyridine-?N:N'] 4,4'-bipyridine solvate].
| S-EPMC2969491 | biostudies-literature
Unknown catena-Poly[[[(1,10-phenanthroline-κN,N')zinc]-μ-pyridine-2,3-dicarboxyl-ato-κN,O:O,O] monohydrate].
| S-EPMC3152098 | biostudies-literature
Unknown catena-Poly[[diaqua-zinc(II)]-?-4,4'-(methyl-enedioxy)-dibenzoato].
| S-EPMC2969040 | biostudies-literature
Unknown catena-Poly[[diaqua-(1H-imidazo[4,5-f][1,10]phenanthroline)cobalt(II)]-?-sulfato].
| S-EPMC2969714 | biostudies-literature