Ontology highlight
ABSTRACT:
SUBMITTER: Brennessel WW
PROVIDER: S-EPMC3470125 | biostudies-literature | 2012 Oct
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20120901 Pt 10
The title salt, [K(C(12)H(24)O(6))][Fe(C(8)H(12))(C(10)H(8))], is the only known naphthalene complex containing iron in a formally negative oxidation state. Each (naphthalene)(1,5-cod)ferrate(-I) anion is in contact with one (18-crown-6)potassium cation via K⋯C contacts to the outer four carbon atoms of the naphthalene ligand (cod = 1,5-cyclo-octa-diene, 18-crown-6 = 1,4,7,10,13,16-hexa-oxacyclo-octa-deca-ne). When using the midpoints of the coordinating olefin bonds, the overall geometry of the ...[more]