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(Acetato-?(2)O,O')[2'-(di-tert-butyl-phosphanyl)-1,1'-biphenyl-?(2)P,C(2)]palladium(II).

ABSTRACT: The structure of the title compound, [Pd(C(2)H(3)O(2))(C(20)H(26)P)], shows a distorted square-planar geometry for the Pd(II) atom, with significant deviations being evident owing to the asymmetric coordination mode of the acetate ligand. A weak intra-molecular C-H?O inter-action is noted. The crystal studied was a racemic twin.

SUBMITTER: Arderne C

PROVIDER: S-EPMC3470176 | biostudies-literature | 2012 Oct

REPOSITORIES: biostudies-literature

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(Acetato-κ(2)O,O')[2'-(di-tert-butyl-phosphanyl)-1,1'-biphenyl-κ(2)P,C(2)]palladium(II).

Arderne Charmaine C Holzapfel Cedric W CW

Acta crystallographica. Section E, Structure reports online 20120926 Pt 10

The structure of the title compound, [Pd(C(2)H(3)O(2))(C(20)H(26)P)], shows a distorted square-planar geometry for the Pd(II) atom, with significant deviations being evident owing to the asymmetric coordination mode of the acetate ligand. A weak intra-molecular C-H⋯O inter-action is noted. The crystal studied was a racemic twin. ...[more]

PMID: 23125620

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