Unknown

Dataset Information

0

(Acetato-?(2)O,O')[2'-(di-tert-butyl-phosphanyl)-1,1'-biphenyl-?(2)P,C(2)]palladium(II).


ABSTRACT: The structure of the title compound, [Pd(C(2)H(3)O(2))(C(20)H(26)P)], shows a distorted square-planar geometry for the Pd(II) atom, with significant deviations being evident owing to the asymmetric coordination mode of the acetate ligand. A weak intra-molecular C-H?O inter-action is noted. The crystal studied was a racemic twin.

SUBMITTER: Arderne C 

PROVIDER: S-EPMC3470176 | biostudies-literature | 2012 Oct

REPOSITORIES: biostudies-literature

altmetric image

Publications

(Acetato-κ(2)O,O')[2'-(di-tert-butyl-phosphanyl)-1,1'-biphenyl-κ(2)P,C(2)]palladium(II).

Arderne Charmaine C   Holzapfel Cedric W CW  

Acta crystallographica. Section E, Structure reports online 20120926 Pt 10


The structure of the title compound, [Pd(C(2)H(3)O(2))(C(20)H(26)P)], shows a distorted square-planar geometry for the Pd(II) atom, with significant deviations being evident owing to the asymmetric coordination mode of the acetate ligand. A weak intra-molecular C-H⋯O inter-action is noted. The crystal studied was a racemic twin. ...[more]

Similar Datasets

| S-EPMC3470136 | biostudies-literature
| S-EPMC3569185 | biostudies-literature
| S-EPMC2979456 | biostudies-other
| S-EPMC2968877 | biostudies-literature
| S-EPMC3379177 | biostudies-literature
| S-EPMC2969421 | biostudies-literature
| S-EPMC2962041 | biostudies-literature
| S-EPMC2968339 | biostudies-literature
| S-EPMC2915266 | biostudies-literature
| S-EPMC3588282 | biostudies-literature