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Di-?-chlorido-bis-{[2-(di-tert-butyl-phosphan-yl)biphenyl-3-yl-?(2)C(3),P]palladium(II)} dichloro-methane disolvate.

ABSTRACT: The asymmetric unit of the title compound, [Pd(2)Cl(2)(C(20)H(26)P)(2)]·2CH(2)Cl(2), contains one half-mol-ecule of the palladium complex and a dichloro-methane solvent mol-ecule. In the complex, two Pd(II) atoms are bridged by two Cl atoms, with the other two coordination sites occupied by a C atom of the biphenyl system and a P atom, resulting in a distorted square-planar coordination geometry of the Pd(II) atom and a cyclo-metallated four-membered ring. The Pd(2)Cl(2) unit is located about an inversion center. The planes of the rings of the biphenyl system make a dihedral angle of 66.36?(11)°.

SUBMITTER: Holzapfel CW

PROVIDER: S-EPMC3569185 | biostudies-literature | 2013 Feb

REPOSITORIES: biostudies-literature

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Di-μ-chlorido-bis-{[2-(di-tert-butyl-phosphan-yl)biphenyl-3-yl-κ(2)C(3),P]palladium(II)} dichloro-methane disolvate.

Holzapfel Cedric W CW Omondi Bernard B

Acta crystallographica. Section E, Structure reports online 20130109 Pt 2

The asymmetric unit of the title compound, [Pd(2)Cl(2)(C(20)H(26)P)(2)]·2CH(2)Cl(2), contains one half-mol-ecule of the palladium complex and a dichloro-methane solvent mol-ecule. In the complex, two Pd(II) atoms are bridged by two Cl atoms, with the other two coordination sites occupied by a C atom of the biphenyl system and a P atom, resulting in a distorted square-planar coordination geometry of the Pd(II) atom and a cyclo-metallated four-membered ring. The Pd(2)Cl(2) unit is located about an ...[more]

PMID: 23424429

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