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4-{(E)-2-[4-(But-3-en-1-yl-oxy)phen-yl]diazen-1-yl}benzoic acid.


ABSTRACT: The title compound, C(17)H(16)N(2)O(3), has an E conformation about the azobenzene (-N=N-) linkage. The benzene rings are twisted slightly with respect to each other [6.79?(9)°], while the dihedral angle between the plane through the carb-oxy group and the attached benzene ring is 3.2?(2)°. In the crystal, mol-ecules are oriented with the carb-oxy groups head-to-head, forming O-H?O hydrogen-bonded inversion dimers. These dimers are connected by C-H?O hydrogen-bonds into layers lying parallel to the (013) plane.

SUBMITTER: Rahman ML 

PROVIDER: S-EPMC3470328 | biostudies-literature | 2012 Oct

REPOSITORIES: biostudies-literature

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4-{(E)-2-[4-(But-3-en-1-yl-oxy)phen-yl]diazen-1-yl}benzoic acid.

Rahman Md Lutfor ML   Kwong Huey Chong HC   Mohd Yusoff Mashitah M   Hegde Gurumurthy G   Mohamed Tahir Mohamed Ibrahim MI   Rahman Mohamad Zaki Ab MZ  

Acta crystallographica. Section E, Structure reports online 20120919 Pt 10


The title compound, C(17)H(16)N(2)O(3), has an E conformation about the azobenzene (-N=N-) linkage. The benzene rings are twisted slightly with respect to each other [6.79 (9)°], while the dihedral angle between the plane through the carb-oxy group and the attached benzene ring is 3.2 (2)°. In the crystal, mol-ecules are oriented with the carb-oxy groups head-to-head, forming O-H⋯O hydrogen-bonded inversion dimers. These dimers are connected by C-H⋯O hydrogen-bonds into layers lying parallel to  ...[more]

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