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Direct stereospecific amination of alkyl and aryl pinacol boronates.

ABSTRACT: The direct amination of alkyl and aryl pinacol boronates is accomplished with lithiated methoxyamine. This reaction directly provides aliphatic and aromatic amines, stereospecifically, and without preactivation of the boronate substrate.

SUBMITTER: Mlynarski SN 

PROVIDER: S-EPMC3481838 | biostudies-literature | 2012 Oct

REPOSITORIES: biostudies-literature

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Direct stereospecific amination of alkyl and aryl pinacol boronates.

Mlynarski Scott N SN   Karns Alexander S AS   Morken James P JP  

Journal of the American Chemical Society 20120924 40

The direct amination of alkyl and aryl pinacol boronates is accomplished with lithiated methoxyamine. This reaction directly provides aliphatic and aromatic amines, stereospecifically, and without preactivation of the boronate substrate. ...[more]

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