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Bis(2,2':6',2''-terpyridine)-ruthenium(II) bis-(perchlorate) hemihydrate.

ABSTRACT: The asymmetric unit of the title compound, [Ru(C(15)H(11)N(3))(2)](ClO(4))(2)·0.5H(2)O, contains one ruthenium-terpiridine complex cation, two perchlorate anions and one half-mol-ecule of water. Face-to-face and face-to-edge ?-stacking inter-actions between terpyridine units [centroid-centroid distances = 3.793?(2) and 3.801?(2)? Å] stabilize the crystal lattice The partially occupied water mol-ecule inter-acts with two perchlorate ions via O-H?O hydrogen bonds. In the crystal lattice, the complex cations, perchlorate ion-water pairs and the second perchlorate anions are arranged into columns along b direction.

SUBMITTER: Kozlowska M

PROVIDER: S-EPMC3515152 | biostudies-literature | 2012 Nov

REPOSITORIES: biostudies-literature

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Bis(2,2':6',2''-terpyridine)-ruthenium(II) bis-(perchlorate) hemihydrate.

Kozlowska Mariana M Rodziewicz Pawel P Brus Diana Malgorzata DM Breczko Joanna J Brzezinski Krzysztof K

Acta crystallographica. Section E, Structure reports online 20121027 Pt 11

The asymmetric unit of the title compound, [Ru(C(15)H(11)N(3))(2)](ClO(4))(2)·0.5H(2)O, contains one ruthenium-terpiridine complex cation, two perchlorate anions and one half-mol-ecule of water. Face-to-face and face-to-edge π-stacking inter-actions between terpyridine units [centroid-centroid distances = 3.793 (2) and 3.801 (2) Å] stabilize the crystal lattice The partially occupied water mol-ecule inter-acts with two perchlorate ions via O-H⋯O hydrogen bonds. In the crystal lattice, the compl ...[more]

PMID: 23284379

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