Ontology highlight
ABSTRACT:
SUBMITTER: Sanchez L
PROVIDER: S-EPMC3528832 | biostudies-literature | 2012 Dec
REPOSITORIES: biostudies-literature
Sanchez Luis L Smith Amos B AB
Organic letters 20121206 24
The design, synthesis, and validation of linchpins for Anion Relay Chemistry (ARC) capable of iterative silyl group migrations have been achieved. This tactic permits "long-range" relocation of negative charge across space, to generate reactive distal nucleophilic centers for both alkylation and palladium-catalyzed coupling reactions. ...[more]