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Hexaaqua-cobalt(II) 2,2'-[naphthalene-1,8-diylbis(-oxy)]diacetate dihydrate.

ABSTRACT: In the title compound, [Co(H(2)O)(6)](C(14)H(10)O(6))·2H(2)O, the 2,2'-[naphthalene-1,8-diylbis(-oxy)]diacetate dianion L is not coordinated to the Co(II) ion. The asymmetric unit contains half of the L dianion, half of a [Co(H(2)O)(6)](2+) cation (both molecules being completed by inversion symmetry), and one water mol-ecule. The crystal packing features O-H?O hydrogen bonding between the carboxyl-ate groups, the aqua ligands and the hydrate water mol-ecules.

SUBMITTER: Shi HF

PROVIDER: S-EPMC3569200 | biostudies-literature | 2013 Feb

REPOSITORIES: biostudies-literature

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Hexaaqua-cobalt(II) 2,2'-[naphthalene-1,8-diylbis(-oxy)]diacetate dihydrate.

Shi Hui Fang HF Wu Tao T Jiang Peng Gang PG Hao Zhi Z Zhang Miao Miao MM

Acta crystallographica. Section E, Structure reports online 20130112 Pt 2

In the title compound, [Co(H(2)O)(6)](C(14)H(10)O(6))·2H(2)O, the 2,2'-[naphthalene-1,8-diylbis(-oxy)]diacetate dianion L is not coordinated to the Co(II) ion. The asymmetric unit contains half of the L dianion, half of a [Co(H(2)O)(6)](2+) cation (both molecules being completed by inversion symmetry), and one water mol-ecule. The crystal packing features O-H⋯O hydrogen bonding between the carboxyl-ate groups, the aqua ligands and the hydrate water mol-ecules. ...[more]

PMID: 23424401

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