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Transition metal photoredox catalysis of radical thiol-ene reactions.


ABSTRACT: We describe the anti-Markovnikov hydrothiolation of olefins using visible-light-absorbing transition metal photocatalysts. The key thiyl radical intermediates are generated upon quenching of photoexcited Ru*(bpz)3(2) with a variety of thiols. The adducts of a wide variety of olefins and thiols are formed in excellent yield (73-99%).

SUBMITTER: Tyson EL 

PROVIDER: S-EPMC3573243 | biostudies-literature | 2013 Mar

REPOSITORIES: biostudies-literature

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Transition metal photoredox catalysis of radical thiol-ene reactions.

Tyson Elizabeth L EL   Ament Michael S MS   Yoon Tehshik P TP  

The Journal of organic chemistry 20121112 5


We describe the anti-Markovnikov hydrothiolation of olefins using visible-light-absorbing transition metal photocatalysts. The key thiyl radical intermediates are generated upon quenching of photoexcited Ru*(bpz)3(2) with a variety of thiols. The adducts of a wide variety of olefins and thiols are formed in excellent yield (73-99%). ...[more]

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