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Hexa-?2-acetato-hexa-n-butyl-hexa-?3-oxido-tin(IV) toluene monosolvate.

ABSTRACT: The title compound, [Sn6(C4H9)6(CH3COO)6O6]·C7H8, has one half-toluene mol-ecule and one half-organotin mol-ecule in the asymmetric unit. The latter is situated about an inversion centre and belongs to the class of hexa-meric monoorganooxo-tin carboxyl-ates with a hexa-gonal prismatic or 'drum-like' motif of the central tin-oxygen core. Two Sn3O3 rings in a flat-chair conformation are linked via six Sn-O bonds and six bridging acetate groups. All Sn atoms have approximate octa-hedral coordination geometry. The Sn-O bonds which are trans to the alkyl group are significantly shorter than the others. One butyl group is disordered over two different sites, with occupancies of 0.9:0.1. Very large atomic displacement parameters of the toluene mol-ecule indicate an unresolvable disorder about the twofold axis.

SUBMITTER: Reichelt M

PROVIDER: S-EPMC3588278 | biostudies-literature | 2013 Jan

REPOSITORIES: biostudies-literature

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Hexa-μ2-acetato-hexa-n-butyl-hexa-μ3-oxido-tin(IV) toluene monosolvate.

Reichelt Martin M Reuter Hans H

Acta crystallographica. Section E, Structure reports online 20121205 Pt 1

The title compound, [Sn6(C4H9)6(CH3COO)6O6]·C7H8, has one half-toluene mol-ecule and one half-organotin mol-ecule in the asymmetric unit. The latter is situated about an inversion centre and belongs to the class of hexa-meric monoorganooxo-tin carboxyl-ates with a hexa-gonal prismatic or 'drum-like' motif of the central tin-oxygen core. Two Sn3O3 rings in a flat-chair conformation are linked via six Sn-O bonds and six bridging acetate groups. All Sn atoms have approximate octa-hedral coordinatio ...[more]

PMID: 23476337

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