Ontology highlight
ABSTRACT:
SUBMITTER: Reichelt M
PROVIDER: S-EPMC3588278 | biostudies-literature | 2013 Jan
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20121205 Pt 1
The title compound, [Sn6(C4H9)6(CH3COO)6O6]·C7H8, has one half-toluene mol-ecule and one half-organotin mol-ecule in the asymmetric unit. The latter is situated about an inversion centre and belongs to the class of hexa-meric monoorganooxo-tin carboxyl-ates with a hexa-gonal prismatic or 'drum-like' motif of the central tin-oxygen core. Two Sn3O3 rings in a flat-chair conformation are linked via six Sn-O bonds and six bridging acetate groups. All Sn atoms have approximate octa-hedral coordinatio ...[more]