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Chlorido{N-[2-(diphenyl-phosphan-yl)benzyl-idene]-2,6-diisopropyl-aniline-?P}gold(I) chloro-form 0.25-solvate.

ABSTRACT: The asymmetric unit of the title compound, [AuCl(C31H32NP)]·0.25CHCl3, contains two independent complex mol-ecules and half a chloro-form solvent mol-ecule, which is disordered across an inversion center. The Au(I) ions are each coordinated in a slightly distorted linear environment, with P-Au-Cl angles of 177.20?(4) and 178.54?(4)°.

SUBMITTER: Chiririwa H

PROVIDER: S-EPMC3588368 | biostudies-literature | 2013 Jan

REPOSITORIES: biostudies-literature

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Chlorido{N-[2-(diphenyl-phosphan-yl)benzyl-idene]-2,6-diisopropyl-aniline-κP}gold(I) chloro-form 0.25-solvate.

Chiririwa Haleden H Davis Wade L WL

Acta crystallographica. Section E, Structure reports online 20121212 Pt 1

The asymmetric unit of the title compound, [AuCl(C31H32NP)]·0.25CHCl3, contains two independent complex mol-ecules and half a chloro-form solvent mol-ecule, which is disordered across an inversion center. The Au(I) ions are each coordinated in a slightly distorted linear environment, with P-Au-Cl angles of 177.20 (4) and 178.54 (4)°. ...[more]

PMID: 23476336

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