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Chlorido{[(E)-2-(diphenyl-phosphan-yl)benzyl-idene](furan-2-ylmeth-yl)amine-?P}gold(I).

ABSTRACT: In the title complex, [AuCl(C24H20NOP)], the ligand has N, P and O electron-donating atoms but the Au(I) atom is coordinated only by the 'soft' P atom and an additional Cl atom in an almost linear fashion. Important geometrical parameters include Au-P = 2.2321?(13)?Å, Au-Cl = 2.2820?(13)?Å and P-Au-Cl = 176.49?(5)°. The furan ring is disordered over two positions in a 0.51?(2):0.49?(2) ratio.

SUBMITTER: Chiririwa H

PROVIDER: S-EPMC3588354 | biostudies-literature | 2013 Jan

REPOSITORIES: biostudies-literature

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Chlorido{[(E)-2-(diphenyl-phosphan-yl)benzyl-idene](furan-2-ylmeth-yl)amine-κP}gold(I).

Chiririwa Haleden H Davis Wade L WL

Acta crystallographica. Section E, Structure reports online 20121215 Pt 1

In the title complex, [AuCl(C24H20NOP)], the ligand has N, P and O electron-donating atoms but the Au(I) atom is coordinated only by the 'soft' P atom and an additional Cl atom in an almost linear fashion. Important geometrical parameters include Au-P = 2.2321 (13) Å, Au-Cl = 2.2820 (13) Å and P-Au-Cl = 176.49 (5)°. The furan ring is disordered over two positions in a 0.51 (2):0.49 (2) ratio. ...[more]

PMID: 23476348

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Chlorido{N-[(E)-2-(diphenyl-phosphan-yl)benzyl-idene]-2-(thio-phen-2-yl)ethan-amine-?P}gold(I).

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