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(1RS,2RS)-4,4'-(1-Aza-niumyl-2-hy-droxy-ethane-1,2-di-yl)dipyridinium tetra-chlorido-platinate(II) chloride.

ABSTRACT: The title compound, (C12H16N3O)[PtCl4]Cl, consists of a 4,4'-(1-aza-niumyl-2-hy-droxy-ethane-1,2-di-yl)dipyridinium trication, a square-planar tetra-chloridoplatinate(II) dianion and a chloride ion. In the cation, the pyridinium rings attached to the central 1-aza-niumyl-2-hy-droxy-ethane fragment have an anti conformation, as indicated by the central C-C-C-C torsion angle of -166.5?(6)°, and they are inclined to one another by 63.5?(4)°. In the crystal, the cations and anions are linked through N-H?Cl and O-H?Cl hydrogen bonds. There are also ?-? contacts [centroid-centroid distances = 3.671?(4) and 3.851?(4)?Å] and a number of C-H?Cl inter-actions present, consolidating the formation of a three-dimensional supra-molecular structure.

SUBMITTER: Campos-Gaxiola JJ 

PROVIDER: S-EPMC3588516 | biostudies-literature | 2013 Mar

REPOSITORIES: biostudies-literature

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(1RS,2RS)-4,4'-(1-Aza-niumyl-2-hy-droxy-ethane-1,2-di-yl)dipyridinium tetra-chlorido-platinate(II) chloride.

Campos-Gaxiola José J JJ   Almaral-Sanchez Jorge L JL   Cruz-Enríquez Adriana A   Höpfl Herbert H   Parra-Hake Miguel M  

Acta crystallographica. Section E, Structure reports online 20130220 Pt 3

The title compound, (C12H16N3O)[PtCl4]Cl, consists of a 4,4'-(1-aza-niumyl-2-hy-droxy-ethane-1,2-di-yl)dipyridinium trication, a square-planar tetra-chloridoplatinate(II) dianion and a chloride ion. In the cation, the pyridinium rings attached to the central 1-aza-niumyl-2-hy-droxy-ethane fragment have an anti conformation, as indicated by the central C-C-C-C torsion angle of -166.5 (6)°, and they are inclined to one another by 63.5 (4)°. In the crystal, the cations and anions are linked through  ...[more]

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