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Chlorido{N-[(diethyl-amino)-dimethyl-sil-yl]anilido-?N}(N,N,N',N'-tetra-methyl-ethane-1,2-diamine-?(2) N,N')iron(II).

ABSTRACT: In the title iron(II) complex, [Fe(C12H21N2Si)Cl(C6H16N2)], the Fe(II) cation is coordinated by two N atoms from the tetramethylethane-1,2-diamine ligand [Fe-N = 2.191?(5) and 2.215?(4)?Å], one N atom from the N-[(diethyl-amino)-dimethyl-sil-yl]anilide ligand [Fe-N = 1.943?(4)?Å] and a chloride ligand [Fe-Cl = 2.2798?(16)?Å] in a distorted tetra-hedral geometry. The N-Si-N angle is 113.9?(3)°. The crystal packing exhibits no short inter-molecular contacts.

SUBMITTER: Chen J

PROVIDER: S-EPMC3588711 | biostudies-literature | 2012 Dec

REPOSITORIES: biostudies-literature

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Chlorido{N-[(diethyl-amino)-dimethyl-sil-yl]anilido-κN}(N,N,N',N'-tetra-methyl-ethane-1,2-diamine-κ(2) N,N')iron(II).

Chen Juan J

Acta crystallographica. Section E, Structure reports online 20121103 Pt 12

In the title iron(II) complex, [Fe(C12H21N2Si)Cl(C6H16N2)], the Fe(II) cation is coordinated by two N atoms from the tetramethylethane-1,2-diamine ligand [Fe-N = 2.191 (5) and 2.215 (4) Å], one N atom from the N-[(diethyl-amino)-dimethyl-sil-yl]anilide ligand [Fe-N = 1.943 (4) Å] and a chloride ligand [Fe-Cl = 2.2798 (16) Å] in a distorted tetra-hedral geometry. The N-Si-N angle is 113.9 (3)°. The crystal packing exhibits no short inter-molecular contacts. ...[more]

PMID: 23468676

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