Unknown

Dataset Information

0

Dichlorido{N,N-dimethyl-N'-[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-?N,N',N''}zinc.

ABSTRACT: The asymmetric unit of the title compound, [ZnCl(2)(C(11)H(17)N(3))], contains two independent penta-coordinate Zn(II) complex mol-ecules. In each mol-ecule, the metal atom is coordinated by an N,N',N''-tridenate Schiff base and two Cl atoms in a distorted square-pyramidal geometry. The two mol-ecules differ little in their geometry, but more in their inter-molecular inter-actions. In the crystal, adjacent mol-ecules are connected via C-H?Cl inter-actions into a three-dimensional supra-molecular structure. The network is supplemented by ?-? inter-actions formed between the aromatic rings of pairs of the symmetry-related mol-ecules [centroid-centroid distances = 3.6255?(10) and 3.7073?(10)?Å]. The crystal lattice contains void spaces with a size of 52?Å(3).

SUBMITTER: Suleiman Gwaram N 

PROVIDER: S-EPMC3212119 | biostudies-literature | 2011 Aug

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Dichlorido{N,N-dimethyl-N'-[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-κN,N',N''}zinc.

Suleiman Gwaram Nura N   Khaledi Hamid H   Mohd Ali Hapipah H  

Acta crystallographica. Section E, Structure reports online 20110706 Pt 8

The asymmetric unit of the title compound, [ZnCl(2)(C(11)H(17)N(3))], contains two independent penta-coordinate Zn(II) complex mol-ecules. In each mol-ecule, the metal atom is coordinated by an N,N',N''-tridenate Schiff base and two Cl atoms in a distorted square-pyramidal geometry. The two mol-ecules differ little in their geometry, but more in their inter-molecular inter-actions. In the crystal, adjacent mol-ecules are connected via C-H⋯Cl inter-actions into a three-dimensional supra-molecular  ...[more]

Similar Datasets

Unknown Dichlorido{N-[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine}copper(II).
| S-EPMC2968900 | biostudies-literature
Unknown Dichlorido{N,N-dimethyl-N'-[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-?N,N',N''}copper(II).
| S-EPMC2979170 | biostudies-literature
Unknown Dichlorido{N,N-dimethyl-N'-[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-κN,N',N''}manganese(II).
| S-EPMC3051723 | biostudies-literature
Unknown Dichlorido{N-[1-(pyrazin-2-yl)ethyl-idene-κN]ethane-1,2-diamine-κN,N'}zinc.
| S-EPMC3246976 | biostudies-literature
Unknown Dichlorido{N,N-dimethyl-N'-[1-(pyridin-2-yl)ethyl-idene]ethane-1,2-diamine-κN,N',N''}cadmium.
| S-EPMC3051925 | biostudies-literature
Unknown {N,N'-Bis[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-?N,N',N'',N'''}(thio-cyanato-?N)zinc(II) perchlorate.
| S-EPMC3006726 | biostudies-literature
Unknown Aqua-{N,N-dimethyl-N'-[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-κN,N',N''}bis-(thio-cyanato-κN)nickel(II).
| S-EPMC3099768 | biostudies-literature
Unknown Bis{N-methyl-N'-[1-(pyridin-2-yl)ethyl-idene]ethane-1,2-diamine}-zinc bis-(perchlorate).
| S-EPMC3212129 | biostudies-literature
Unknown Bromido{N-methyl-N'-[1-(2-pyrid-yl)ethyl-idene]ethane-1,2-diamine-?N,N',N''}-(thio-cyanato-?N)-copper(II).
| S-EPMC3007341 | biostudies-literature
Unknown Diiodido[N'-(2-methoxy-benzyl-idene)-N,N-dimethyl-ethane-1,2-diamine]zinc(II).
| S-EPMC2970288 | biostudies-literature