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Bis{bis-[2-(diisopropyl-phosphan-yl)phen-yl]phosphanido-?(3) P,P',P''}chloridonickel(II).

ABSTRACT: In the title compound, [Ni(C24H36P3)Cl], the Ni(II) atom adopts a distorted square-planar geometry with the two neutral P atoms of the tridentate ligand trans to one another. Bond lengths and angles of the phosphide P atom feature a pyramidal geometry of the donor atom, which forms a single bond with the Ni(II) atom, retaining a stereochemically active lone pair.

SUBMITTER: Tedesco C

PROVIDER: S-EPMC3588721 | biostudies-literature | 2012 Dec

REPOSITORIES: biostudies-literature

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Bis{bis-[2-(diisopropyl-phosphan-yl)phen-yl]phosphanido-κ(3) P,P',P''}chloridonickel(II).

Tedesco Consiglia C Lamberti Marina M Mazzeo Mina M

Acta crystallographica. Section E, Structure reports online 20121107 Pt 12

In the title compound, [Ni(C24H36P3)Cl], the Ni(II) atom adopts a distorted square-planar geometry with the two neutral P atoms of the tridentate ligand trans to one another. Bond lengths and angles of the phosphide P atom feature a pyramidal geometry of the donor atom, which forms a single bond with the Ni(II) atom, retaining a stereochemically active lone pair. ...[more]

PMID: 23468686

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