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[1,2-Bis(diisopropyl-phosphan-yl)ethane-?(2) P,P'](carbonato-?(2) O,O')nickel(II).

ABSTRACT: In the crystal of the title compound, [Ni(CO3)(C14H32P2)], the metal center in each of three independent mol-ecules shows slight tetra-hedral distortion from ideal square-planar coordination geometry, with angles between the normals to the planes defined by the cis-P-Ni-P and cis-O-Ni-O fragments of 3.92?(17), 0.70?(16) and 2.17?(14)° in the three mol-ecules. In the crystal, there are inter-molecular C-H?O hydrogen bonds that show a laminar growth in the ab plane.

SUBMITTER: Morales-Becerril I

PROVIDER: S-EPMC3629481 | biostudies-literature | 2013 Apr

REPOSITORIES: biostudies-literature

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[1,2-Bis(diisopropyl-phosphan-yl)ethane-κ(2) P,P'](carbonato-κ(2) O,O')nickel(II).

Morales-Becerril Illan I Flores-Alamo Marcos M Garcia Juventino J JJ

Acta crystallographica. Section E, Structure reports online 20130313 Pt 4

In the crystal of the title compound, [Ni(CO3)(C14H32P2)], the metal center in each of three independent mol-ecules shows slight tetra-hedral distortion from ideal square-planar coordination geometry, with angles between the normals to the planes defined by the cis-P-Ni-P and cis-O-Ni-O fragments of 3.92 (17), 0.70 (16) and 2.17 (14)° in the three mol-ecules. In the crystal, there are inter-molecular C-H⋯O hydrogen bonds that show a laminar growth in the ab plane. ...[more]

PMID: 23633999

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