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1,1'-Bis[bis-(4-meth-oxy-phen-yl)phosphan-yl]ferrocene.

ABSTRACT: In the crystal structure of the title substituted ferrocene complex, [Fe(C??H??O?P)?], the Fe(II) atom lies on a twofold rotation axis, giving an eclipsed cyclo-penta-dienyl conformation with a ring centroid separation of 3.292?(7)?Å and an Fe-C bond-length range of 2.0239?(15)-2.0521?(15)?Å. In the ligand, the cyclo-penta-dienyl ring forms dihedral angles of 60.36?(6) and 82.93?(6)° with the two benzene rings of the diphenyl-phosphine group, while the dihedral angle between the benzene rings is 67.4?(5)°.

SUBMITTER: Ren X

PROVIDER: S-EPMC3393188 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

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1,1'-Bis[bis-(4-meth-oxy-phen-yl)phosphan-yl]ferrocene.

Ren Xinfeng X Wang Le L Li Ya Y

Acta crystallographica. Section E, Structure reports online 20120616 Pt 7

In the crystal structure of the title substituted ferrocene complex, [Fe(C₁₉H₁₈O₂P)₂], the Fe(II) atom lies on a twofold rotation axis, giving an eclipsed cyclo-penta-dienyl conformation with a ring centroid separation of 3.292 (7) Å and an Fe-C bond-length range of 2.0239 (15)-2.0521 (15) Å. In the ligand, the cyclo-penta-dienyl ring forms dihedral angles of 60.36 (6) and 82.93 (6)° with the two benzene rings of the diphenyl-phosphine group, while the dihedral angle between the benzene rings is ...[more]

PMID: 22807756

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