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Rac-{[2-(Diphenyl-thio-phosphan-yl)ferrocen-yl]meth-yl}trimethyl-ammonium iodide chloro-form monosolvate.

ABSTRACT: The title compound, [Fe(C5H5)(C21H24NPS)]I·CHCl3, is built up from a (ferrocenylmeth-yl)trimethyl-ammonium cation, a iodine anion and a chloro-form solvent mol-ecule, all residing in general positions. The N atom of the ammonium group is displaced by 1.182?(2)?Å from the plane of the substituted cyclo-penta-dienyl (Cp) ring towards the Fe atom, whereas the C atom attached to the same Cp ring is slightly below this plane by -0.128?(2)?Å. These deviations might result from weak agostic interactions between the two H atoms of the CH2 group and the Fe atom.

SUBMITTER: Karpous A

PROVIDER: S-EPMC3588745 | biostudies-literature | 2012 Dec

REPOSITORIES: biostudies-literature

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rac-{[2-(Diphenyl-thio-phosphan-yl)ferrocen-yl]meth-yl}trimethyl-ammonium iodide chloro-form monosolvate.

Karpous Andrei A Voitenko Zoia Z Daran Jean-Claude JC Manoury Eric E

Acta crystallographica. Section E, Structure reports online 20121117 Pt 12

The title compound, [Fe(C5H5)(C21H24NPS)]I·CHCl3, is built up from a (ferrocenylmeth-yl)trimethyl-ammonium cation, a iodine anion and a chloro-form solvent mol-ecule, all residing in general positions. The N atom of the ammonium group is displaced by 1.182 (2) Å from the plane of the substituted cyclo-penta-dienyl (Cp) ring towards the Fe atom, whereas the C atom attached to the same Cp ring is slightly below this plane by -0.128 (2) Å. These deviations might result from weak agostic interaction ...[more]

PMID: 23468710

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