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[1,2-Bis(diphenyl-phosphan-yl)ethane-?(2)P,P']dichloridopalladium(II) dimethyl sulfoxide monosolvate.

ABSTRACT: In the title compound, [PdCl(2)(C(26)H(24)P(2))]·C(2)H(6)OS, the Pd(II) atom adopts a distorted cis-PdCl(2)P(2) square-planar coordination geometry. The five-membered chelate ring adopts an envelope conformation with a methyl-ene C atom in the flap position. The S and C atoms of the dimethyl sulfoxide (DMSO) solvent mol-ecule are disordered over two sets of sites in a 0.8976?(18):0.1024?(18) ratio. The DMSO O atom accepts three C-H?O hydrogen bonds from an adjacent complex mol-ecule.

SUBMITTER: Warad I

PROVIDER: S-EPMC3393233 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

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[1,2-Bis(diphenyl-phosphan-yl)ethane-κ(2)P,P']dichloridopalladium(II) dimethyl sulfoxide monosolvate.

Warad Ismail I Aldwayyan Abdullah S AS Al-Jekhedab Fahad M FM Choudhary M Iqbal MI Yousuf Sammer S

Acta crystallographica. Section E, Structure reports online 20120630 Pt 7

In the title compound, [PdCl(2)(C(26)H(24)P(2))]·C(2)H(6)OS, the Pd(II) atom adopts a distorted cis-PdCl(2)P(2) square-planar coordination geometry. The five-membered chelate ring adopts an envelope conformation with a methyl-ene C atom in the flap position. The S and C atoms of the dimethyl sulfoxide (DMSO) solvent mol-ecule are disordered over two sets of sites in a 0.8976 (18):0.1024 (18) ratio. The DMSO O atom accepts three C-H⋯O hydrogen bonds from an adjacent complex mol-ecule. ...[more]

PMID: 22807801

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