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Catena-Poly[[(4,4'-dimethyl-2,2'-bipyridine-?(2) N,N')cadmium]-di-?-bromido].

ABSTRACT: In the crystal of the title polymeric compound, [CdBr2(C12H12N2)] n , the Cd(II) cation is located on a twofold rotation axis and is six-coordinated in a distorted octa-hedral geometry formed by two N atoms from the 4,4'-dimethyl-2,2'-bipyridine ligand and by four bridging Br(-) anions. The bridging function of the Br(-) anions leads to a polymeric chain running along the c axis. Weak C-H?? inter-actions observed between adjacent chains are effective in the stabilization of the three-dimensional packing.

SUBMITTER: Shirvan SA 

PROVIDER: S-EPMC3588747 | biostudies-literature | 2012 Dec

REPOSITORIES: biostudies-literature

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catena-Poly[[(4,4'-dimethyl-2,2'-bipyridine-κ(2) N,N')cadmium]-di-μ-bromido].

Shirvan Sadif A SA   Haydari Dezfuli Sara S   Khazali Fereydoon F   Borsalani Ali A  

Acta crystallographica. Section E, Structure reports online 20121117 Pt 12

In the crystal of the title polymeric compound, [CdBr2(C12H12N2)] n , the Cd(II) cation is located on a twofold rotation axis and is six-coordinated in a distorted octa-hedral geometry formed by two N atoms from the 4,4'-dimethyl-2,2'-bipyridine ligand and by four bridging Br(-) anions. The bridging function of the Br(-) anions leads to a polymeric chain running along the c axis. Weak C-H⋯π inter-actions observed between adjacent chains are effective in the stabilization of the three-dimensional  ...[more]

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