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Catena-Poly[[(5,5'-dimethyl-2,2'-bipyridine-?(2)N,N')cadmium]-di-?-bromido].


ABSTRACT: In the crystal of the title polymeric compound, [CdBr(2)(C(12)H(12)N(2))](n), the Cd(II) cation is located on a twofold rotation axis. The Cd(II) cation is six-coordinated in a distorted octa-hedral geometry formed by two N atoms from the 5,5'-dimethyl-2,2'-bipyridine ligand and four bridging Br(-) anions. The bridging function of the Br(-) anions leads to a polymeric chain running along the c axis.

SUBMITTER: Shirvan SA 

PROVIDER: S-EPMC3379185 | biostudies-literature | 2012 Jun

REPOSITORIES: biostudies-literature

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catena-Poly[[(5,5'-dimethyl-2,2'-bipyridine-κ(2)N,N')cadmium]-di-μ-bromido].

Shirvan Sadif A SA   Haydari Dezfuli Sara S  

Acta crystallographica. Section E, Structure reports online 20120531 Pt 6


In the crystal of the title polymeric compound, [CdBr(2)(C(12)H(12)N(2))](n), the Cd(II) cation is located on a twofold rotation axis. The Cd(II) cation is six-coordinated in a distorted octa-hedral geometry formed by two N atoms from the 5,5'-dimethyl-2,2'-bipyridine ligand and four bridging Br(-) anions. The bridging function of the Br(-) anions leads to a polymeric chain running along the c axis. ...[more]

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