Ontology highlight
ABSTRACT:
SUBMITTER: Olsson D
PROVIDER: S-EPMC3588760 | biostudies-literature | 2012 Dec
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Structure reports online 20121124 Pt 12
The Pd(II) atom in the title compound, [Pd(C24H49P2)Cl], has a distorted square-planar CClP2 coordination geometry with the P,C,P'-tridentate ligand forming two five-membered metallacycles. The cyclo-hexane ring is aligned with the Pd(II) coordination plane due to C-H activation in an equatorial position, giving a tri-equatorial conformation of the cyclo-hexyl ring. ...[more]