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Cis-{2,6-Bis[(di-tert-butyl-phosphan-yl)meth-yl]cyclo-hexyl-?(3) P,C (1),P'}chloridopalladium(II).

ABSTRACT: The Pd(II) atom in the title compound, [Pd(C24H49P2)Cl], has a distorted square-planar CClP2 coordination geometry with the P,C,P'-tridentate ligand forming two five-membered metallacycles. The cyclo-hexane ring is aligned with the Pd(II) coordination plane due to C-H activation in an equatorial position, giving a tri-equatorial conformation of the cyclo-hexyl ring.

SUBMITTER: Olsson D 

PROVIDER: S-EPMC3588760 | biostudies-literature | 2012 Dec

REPOSITORIES: biostudies-literature

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cis-{2,6-Bis[(di-tert-butyl-phosphan-yl)meth-yl]cyclo-hexyl-κ(3) P,C (1),P'}chloridopalladium(II).

Olsson Daniel D   Janse van Rensburg J Marthinus JM   Wendt Ola F OF  

Acta crystallographica. Section E, Structure reports online 20121124 Pt 12

The Pd(II) atom in the title compound, [Pd(C24H49P2)Cl], has a distorted square-planar CClP2 coordination geometry with the P,C,P'-tridentate ligand forming two five-membered metallacycles. The cyclo-hexane ring is aligned with the Pd(II) coordination plane due to C-H activation in an equatorial position, giving a tri-equatorial conformation of the cyclo-hexyl ring. ...[more]

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