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A highly selective and non-reaction based chemosensor for the detection of Hg2+ ions using a luminescent iridium(III) complex.

ABSTRACT: We report herein a novel luminescent iridium(III) complex with two hydrophobic carbon chains as a non-reaction based chemosensor for the detection of Hg(2+) ions in aqueous solution (<0.002% of organic solvent attributed to the probe solution). Upon the addition of Hg(2+) ions, the emission intensity of the complex was significantly enhanced and this change could be monitored by the naked eye under UV irradiation. The iridium(III) complex shows high specificity for Hg(2+) ions over eighteen other cations. The system is capable of detecting micromolar levels of Hg(2+) ions, which is within the range of many chemical systems.

SUBMITTER: Chan DS

PROVIDER: S-EPMC3606269 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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A highly selective and non-reaction based chemosensor for the detection of Hg2+ ions using a luminescent iridium(III) complex.

Chan Daniel Shiu-Hin DS Fu Wai-Chung WC Wang Modi M Liu Li-Juan LJ Leung Chung-Hang CH Ma Dik-Lung DL

PloS one 20130322 3

We report herein a novel luminescent iridium(III) complex with two hydrophobic carbon chains as a non-reaction based chemosensor for the detection of Hg(2+) ions in aqueous solution (<0.002% of organic solvent attributed to the probe solution). Upon the addition of Hg(2+) ions, the emission intensity of the complex was significantly enhanced and this change could be monitored by the naked eye under UV irradiation. The iridium(III) complex shows high specificity for Hg(2+) ions over eighteen othe ...[more]

PMID: 23533670

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